Syntheses, Structures, Photochemical and Magnetic Properties of Novel Divalent Cd/Mn Coordination Polymers Based on a Semirigid Tripodal Carboxylate Ligand
- Jiehu Cui (1974502)
- Qingxiang Yang (1889461)
- Yizhi Li (1349064)
- Zijian Guo (140945)
- Hegen Zheng (1850344)
DOIAbstract
The reactions of a semirigid tripodal carboxylic ligand, 3,5-bi(4-carboxy-phenoxy)-benzoic acid (H<sub>3</sub>BCPBA) with Cd(NO<sub>3</sub>)<sub>2</sub>/Mn(NO<sub>3</sub>)<sub>2</sub> afford five novel complexes, {[Cd<sub>3</sub>(BCPBA)<sub>2</sub>·(DMA)<sub>2</sub>·(H<sub>2</sub>O)<sub>5</sub>]·7H<sub>2</sub>O·2DMA}<sub><i>n</i></sub> (<b>1</b>), {[Cd<sub>3</sub>(BCPBA)<sub>2</sub>(L<sup>1</sup>)(H<sub>2</sub>O)<sub>6</sub>]·(L<sup>1</sup>)}<sub><i>n</i></sub> (L<sup>1</sup> = 4-[(E)-4-pyridinylazo]pyridine) (<b>2</b>), {[Cd<sub>3</sub>(BCPBA)<sub>2</sub>(L<sup>2</sup>)·(H<sub>2</sub>O)<sub>3</sub>(DMF)<sub>2</sub>]·2DMF}<sub><i>n</i></sub> (L<sup>2</sup> = 1,3-bis(4-pyridyl)propane) (<b>3</b>), {[Mn<sub>3</sub>(BCPBA)<sub>2</sub>...
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