Copper Ion Mediated Selective Cleavage of C–S Bond in Ferrocenylthiosemicarbazone Forming Mixed Geometrical [(PPh3)Cu(μ-S)2Cu(PPh3)2] Having Cu2S2 Core: Toward a New Avenue in Copper–Sulfur Chemistry

Rathinasabapathi Prabhakaran (2102278)
Palaniappan Kalaivani (2102287)
Somanur V. Renukadevi (2102284)
Rui Huang (141490)
Kittusamy Senthilkumar (2102281)
Ramasamy Karvembu (1519201)
Karuppannan Natarajan (1997152)

Publication date

February 2016

DOI

10.1021/ic2022616.s001

Abstract

Unprecedented selective cleavage of the carbon–sulfur bond of the ferrocenylthiosemicarbazone moiety has been observed for the first time, resulting in the formation of mixed geometrical binuclear copper complex [(PPh3)Cu(μ-S)2Cu(PPh3)2]. Upon trying direct synthesis of the title complex, an unusual tetranuclear [Cu4(μ3-Cl)4(PPh3)4] cubane resulted

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Copper Ion Mediated Selective Cleavage of C–S Bond in Ferrocenylthiosemicarbazone Forming Mixed Geometrical [(PPh<sub>3</sub>)Cu(μ-S)<sub>2</sub>Cu(PPh<sub>3</sub>)<sub>2</sub>] Having Cu<sub>2</sub>S<sub>2</sub> Core: Toward a New Avenue in Copper–Sulfur Chemistry

Abstract

Extracted data

Copper Ion Mediated Selective Cleavage of C–S Bond in Ferrocenylthiosemicarbazone Forming Mixed Geometrical [(PPh<sub>3</sub>)Cu(μ-S)<sub>2</sub>Cu(PPh<sub>3</sub>)<sub>2</sub>] Having Cu<sub>2</sub>S<sub>2</sub> Core: Toward a New Avenue in Copper–Sulfur Chemistry

Abstract

Extracted data

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