Mechanically Induced Scission and Subsequent Thermal Remending of Perfluorocyclobutane Polymers

Perfluorocyclobutane (PFCB) polymer solutions were subjected to pulsed ultrasound, leading to mechanically induced chain scission and molecular weight degradation. ¹⁹F NMR revealed that the new, mechanically generated end groups are trifluorovinyl ethers formed by cycloreversion of the PFCB groups, a process that differs from thermal degradation pathways. One consequence of the mechanochemical process is that the trifluorovinyl ether end groups can be remended simply by subjecting the polymer solution to the original polymerization conditions, that is, heating to >150 °C. Stereochemical changes in the PFCBs, in combination with radical trapping experiments, indicate that PFCB scission proceeds via a stepwise mechanism with a 1,4-diradical intermediate, offering a potential mechanism for localized functionalization and cross-linking in regions of high stress