Synthesis of Acyl Terphenyls and Higher Polyaromatics via Base-Promoted C–H Functionalization of Acetylarenes with Arylacetylenes

Elena Yu. Schmidt (2007184)
Elena V. Ivanova (2007187)
Inna V. Tatarinova (2007181)
Igor’ A. Ushakov (821018)
Nadezhda V. Semenova (2624194)
Alexander V. Vashchenko (2624197)
Boris A. Trofimov (723086)

Publication date

April 2016

DOI

10.1021/acs.orglett.6b00782.s001

Abstract

KO<i><sup>t</sup></i>Bu/DMSO-promoted C–H functionalization of acetylarenes with arylacetylenes (100 °C, 30 min), generating β,γ-ethylenic ketones, triggers upon further heating (100 °C, 4 h, with or without acidifying additive) the cascade assembly of acyl terphenyls and higher polyaromatics in good yields

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Synthesis of Acyl Terphenyls and Higher Polyaromatics via Base-Promoted C–H Functionalization of Acetylarenes with Arylacetylenes

Abstract

Extracted data

Synthesis of Acyl Terphenyls and Higher Polyaromatics via Base-Promoted C–H Functionalization of Acetylarenes with Arylacetylenes

Abstract

Extracted data

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