Development of a High-Performance Donor–Acceptor Conjugated Polymer: Synergy in Materials and Device Optimization

The development of a high-performance polymer <b>PBDT-BT</b> for bulk heterojunction solar cell devices is summarized. The polymer was first synthesized by Stille polycondensation, and solar cell devices in conventional geometry were optimized through the use of a lithium salt cathode interlayer reaching 6% power conversion efficiency. Improvements were made to the synthesis of the polymer using Suzuki polycondensation giving high-molecular-weight material in the <i>M</i>_n = 100 kg/mol range. Further device optimization in inverted geometry gave power conversion efficiency of over 9%. The synthesis scalability as well as the batch-to-batch reproducibility of the polymer were extensively investigated