Counter Electrode Impact on Quantum Dot Solar Cell Efficiencies

The counter electrode (CE), despite being as relevant as the photoanode in a quantum dot solar cell (QDSC), has hardly received the scientific attention it deserves. In this study, nine CEs (single-walled carbon nanotubes (SWCNTs), tungsten oxide (WO₃), poly­(3,4-ethylenedioxythiophene) (PEDOT), copper sulfide (Cu₂S), candle soot, functionalized multiwalled carbon nanotubes (F-MWCNTs), reduced tungsten oxide (WO_3–<i>x</i>), carbon fabric (C-Fabric), and C-Fabric/WO_3–<i>x</i>) were prepared by using low-cost components and facile procedures. QDSCs were fabricated with a TiO₂/CdS film which served as a common photoanode for all CEs. The power conversion efficiencies (PCEs) were 2.02, 2.1, 2.79, 2.88, 2.95, 3.78, 3.66, 3.96, and 4.6%, respectively, and the incident photon to current conversion efficiency response was also found to complement the PCE response. Among all CEs employed here, C-Fabric/WO_3–<i>x</i> outperforms all the other CEs, for the synergy between C-Fabric and WO_3–<i>x</i> comes to the fore during cell operation. The low sheet resistance of C-Fabric and its high surface area due to the meshlike morphology enables high WO_3–<i>x</i> loading during electrodeposition, and the good electrocatalytic activity of WO_3–<i>x</i>, the very low overpotential, and its high electrical conductivity that facilitate electron transfer to the electrolyte are responsible for the superior PCE. WO₃-based electrodes have not been used until date in QDSCs; the ease of fabrication of WO₃ films and their good chemical stability and scalability also favor their application to QDSCs. Futuristic possibilities for other novel composite CEs are also discussed. We anticipate this study to be useful for a well-rounded development of high-performance QDSCs