Enhancing the High-Voltage Cycling Performance of LiNi_1/3Co_1/3Mn_1/3O₂/Graphite Batteries Using Alkyl 3,3,3-Trifluoropropanoate as an Electrolyte Additive

The present study demonstrates that the use of alkyl 3,3,3-trifluoropropanoate, including methyl 3,3,3-trifluoropropanoate (TFPM) and ethyl 3,3,3-trifluoropropanoate (TFPE), as new electrolyte additive can dramatically enhance the high-voltage performance of LiNi_1/3Co_1/3Mn_1/3O₂/graphite lithium-ion batteries (3.0–4.6 V, vs Li/Li⁺). The capacity retention was significantly increased from 45.6% to 75.4% after 100 charge–discharge cycles due to the addition of 0.2 wt % TFPM in the electrolyte, and significantly increased from 45.6% to 76.1% after 100 charge–discharge cycles due to the addition of 0.5 wt % TFPE in the electrolyte, verifying their suitability in this application. Electrochemical impedance spectroscopy, X-ray diffraction, Fourier transform infrared spectroscopy, scanning electron microscopy, and X-ray photoelectron spectroscopy were employed to study the effect of TFPM and TFPE on cell performance. The data indicates that the improved cycling activity can be ascribed to the participation of TFPM or TFPE in the formation of a thinner cathode/electrolyte interfacial film, thereby enhancing the cell cycling performance owing to a reduced interfacial resistance at high voltage