Studies into the mechanism of cobalt-catalyzed C(sp<sup>2</sup>)–H borylation of five-membered heteroarenes with pinacolborane (HBPin) as the boron source established the catalyst resting state as the <i>trans</i>-cobalt(III) dihydride boryl, <b>(</b><sup><b>iPr</b></sup><b>PNP)Co(H)</b><sub><b>2</b></sub><b>(BPin)</b> (<sup>iPr</sup>PNP = 2,6-(<sup>i</sup>Pr<sub>2</sub>PCH<sub>2</sub>)<sub>2</sub>(C<sub>5</sub>H<sub>3</sub>N)), at both low and high substrate conversions. The overall first-order rate law and observation of a normal deuterium kinetic isotope effect on the borylation of benzofuran versus benzofuran-2-<i>d</i><sub>1</sub> support H<sub>2</sub> reductive elimination from the cobalt(III) dihydride boryl as the turnover-limi...
A study on the iridium-catalyzed C–H borylation of heteroarenes is reported. Several heteroarenes co...
Heterobimetallic Cu–Fe and Zn–Fe complexes catalyze C–H borylation, a transformation that previously...
Among the fundamental transformations that comprise a catalytic cycle for cross coupling, transmetal...
The mechanism for the borylation of an aromatic substrate by a cobalt pincer complex was investigate...
We describe the synthesis of a cobalt(I)–N2 complex (2) supported by a meridional bis-phosphino-bory...
Cobalt(II) dichloride complexes supported by a variety of neutral, tridentate pincer ligands have b...
A family of pincer-ligated cobalt complexes has been synthesized and are active for the catalytic C−...
A bench-stable, 4-aryl-substituted terpyridine supported, high-spin cobalt(II) bis(acetate) comple...
The saturated trihydride IrH3{κ3‐P,O,P‐[xant(PiPr2)2]} (1; xant(PiPr2)2=9,9‐dimethyl‐4,5‐bis(diisopr...
Cobalt dialkyl and bis(carboxylate) complexes bearing α-diimine ligands have been synthesized and d...
Metal-catalyzed C−H activations are environmentally and economically attractive synthetic strategies...
Catalytic C–H borylation using the five-coordinate tris-boryl complex (dippe)Ir(Bpin)<sub>3</sub> ...
We describe the synthesis of a cobalt(I)–N<sub>2</sub> complex (<b>2</b>) supported by a meridional...
To understand better how homogeneous catalysts comprised of two base metals can mimic precious metal...
We have conducted mechanistic investigations using dispersion-corrected hybrid density functional th...
A study on the iridium-catalyzed C–H borylation of heteroarenes is reported. Several heteroarenes co...
Heterobimetallic Cu–Fe and Zn–Fe complexes catalyze C–H borylation, a transformation that previously...
Among the fundamental transformations that comprise a catalytic cycle for cross coupling, transmetal...
The mechanism for the borylation of an aromatic substrate by a cobalt pincer complex was investigate...
We describe the synthesis of a cobalt(I)–N2 complex (2) supported by a meridional bis-phosphino-bory...
Cobalt(II) dichloride complexes supported by a variety of neutral, tridentate pincer ligands have b...
A family of pincer-ligated cobalt complexes has been synthesized and are active for the catalytic C−...
A bench-stable, 4-aryl-substituted terpyridine supported, high-spin cobalt(II) bis(acetate) comple...
The saturated trihydride IrH3{κ3‐P,O,P‐[xant(PiPr2)2]} (1; xant(PiPr2)2=9,9‐dimethyl‐4,5‐bis(diisopr...
Cobalt dialkyl and bis(carboxylate) complexes bearing α-diimine ligands have been synthesized and d...
Metal-catalyzed C−H activations are environmentally and economically attractive synthetic strategies...
Catalytic C–H borylation using the five-coordinate tris-boryl complex (dippe)Ir(Bpin)<sub>3</sub> ...
We describe the synthesis of a cobalt(I)–N<sub>2</sub> complex (<b>2</b>) supported by a meridional...
To understand better how homogeneous catalysts comprised of two base metals can mimic precious metal...
We have conducted mechanistic investigations using dispersion-corrected hybrid density functional th...
A study on the iridium-catalyzed C–H borylation of heteroarenes is reported. Several heteroarenes co...
Heterobimetallic Cu–Fe and Zn–Fe complexes catalyze C–H borylation, a transformation that previously...
Among the fundamental transformations that comprise a catalytic cycle for cross coupling, transmetal...