Discovery of a novel, large pore phase in a bimetallic Al/V metal-organic framework
- Depauw, Hannes
- Nevjestic, Irena
- Wang, Guangbo
- Leus, Karen
- Callens, Freddy
- De Canck, Els
- De Buysser, Klaartje
- Vrielinck, Henk
- Van Der Voort, Pascal
Publication date
January 2017
DOI Publisher
Royal Society of Chemistry (RSC) ISSN
2050-7488Abstract
A new series of bimetallic COMOC-2(V)/DUT-5(Al) frameworks are developed and fully characterized. Electron paramagnetic resonance and transmission electron microscopy confirm the homogeneous dispersion of Al/V in the entire framework. The study of the flexibility by means of CO2 pressure dependent XRPD and high pressure sorption reveals the co-existence of two different large pore phases and a narrow pore phase in the entire pressure regime
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