Poly(styrene) macromercaptanes (Mn = 1900, 3600, and 6100 g mol-1, PDI ≈ 1.2) derived from thiocarbonyl thio capped polymers prepared via reversible addition fragmentation chain transfer polymerization were employed to initiate the ring opening polymerization (ROP) of D,L-lactide under conditions of organo-catalyis employing 4,4-dimethylaminopyridine. Poly(styrene)-block-poly(lactide) polymers of number average molecular weights up to 25,000 g mol-1 (PDI ≈ 1.2 to 1.6) were obtained and characterized via multiple detection size exclusion chromatography (SEC) using refractive index as well as UV detection. In addition, diffusion ordered nuclear magnetic resonance and liquid chromatography at critical conditions (of both polystyrene as well as...
A method for the production of macrocyclic polystyrene via ring closing of a linear !, -dibrominated...
ABSTRACT: The dimethylaluminum compounds {3-tBu-2-(O)C6H3CH=N-R}AlMe2 [R=C6H5 (1); 2,6- iPr2C6H3 (2)...
The research described in this thesis explored the synthesis tlnd characteristltion of biocompatible...
Poly(styrene) macromercaptanes (Mn = 1900, 3600, and 6100 g mol-1, PDI ≈ 1.2) derived from thiocarbo...
International audiencePoly(styrene) macromercaptanes (M-n = 1900, 3600, and 6100 g mo(-1), PDI appro...
The recently introduced procedure of quantitatively switching thiocarbonyl thio capped (RAFT) polyme...
We have synthesized novel biobased and environmental friendly mid-chain functional macrophotoinitiat...
An amino isopropoxyl strontium (Sr-PO) initiator, which was prepared by the reaction of propylene ox...
A recently introduced procedure involving a mechanistic switch from reversible addition-fragmentatio...
Polyether dendrons have been successfully used as macroinitiators for the living ring-opening polyme...
Polyesters and poly(ester carbonates) were synthesized via ring-opening polymerization with new tin(...
Block copolymers of poly(methylphenylsilylene) and poly(styrene) have been conveniently synthesised ...
In this work, we provide new insights into the ring-opening polymerization (ROP) of eutectic mixture...
This contribution reports on the preparation of hyperbranched polymers via thiol–yne photopolymeriza...
The bulk polymerization of styrene (St) was investigated using diethyl 2,3-dicyano-2,3-di(p-tolyl)su...
A method for the production of macrocyclic polystyrene via ring closing of a linear !, -dibrominated...
ABSTRACT: The dimethylaluminum compounds {3-tBu-2-(O)C6H3CH=N-R}AlMe2 [R=C6H5 (1); 2,6- iPr2C6H3 (2)...
The research described in this thesis explored the synthesis tlnd characteristltion of biocompatible...
Poly(styrene) macromercaptanes (Mn = 1900, 3600, and 6100 g mol-1, PDI ≈ 1.2) derived from thiocarbo...
International audiencePoly(styrene) macromercaptanes (M-n = 1900, 3600, and 6100 g mo(-1), PDI appro...
The recently introduced procedure of quantitatively switching thiocarbonyl thio capped (RAFT) polyme...
We have synthesized novel biobased and environmental friendly mid-chain functional macrophotoinitiat...
An amino isopropoxyl strontium (Sr-PO) initiator, which was prepared by the reaction of propylene ox...
A recently introduced procedure involving a mechanistic switch from reversible addition-fragmentatio...
Polyether dendrons have been successfully used as macroinitiators for the living ring-opening polyme...
Polyesters and poly(ester carbonates) were synthesized via ring-opening polymerization with new tin(...
Block copolymers of poly(methylphenylsilylene) and poly(styrene) have been conveniently synthesised ...
In this work, we provide new insights into the ring-opening polymerization (ROP) of eutectic mixture...
This contribution reports on the preparation of hyperbranched polymers via thiol–yne photopolymeriza...
The bulk polymerization of styrene (St) was investigated using diethyl 2,3-dicyano-2,3-di(p-tolyl)su...
A method for the production of macrocyclic polystyrene via ring closing of a linear !, -dibrominated...
ABSTRACT: The dimethylaluminum compounds {3-tBu-2-(O)C6H3CH=N-R}AlMe2 [R=C6H5 (1); 2,6- iPr2C6H3 (2)...
The research described in this thesis explored the synthesis tlnd characteristltion of biocompatible...