Secondary coordination of dichlorodioxomolybdenum(VI) to crown ethers

Levason, W.
Ratnani, R.
Reid, G.
Webster, M.

Publication date

January 2006

DOI

10.1016/j.ica.2006.05.017

Publisher

Elsevier BV

ISSN

0020-1693

Citation count (estimate)

Abstract

The reactions of MoO2Cl2 with 15-crown-5 and 18-crown-6 in ether solution produced crystals of [MoO2Cl2(H2O)(2)] center dot (15-crown-5) and [MoO2Cl2(H2O)(2)] center dot (H2O)(2) center dot (18-crown-6) due to adventitious water. Further hydrolysis lead to crystals of [(H3O) center dot (crown)](2)-[Mo6O19]. The structures of the three complexes are briefly discussed

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Secondary coordination of dichlorodioxomolybdenum(VI) to crown ethers

Abstract

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Secondary coordination of dichlorodioxomolybdenum(VI) to crown ethers

Abstract

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