Add to ORKGThe electrochemistry of mixed conductors is outlined. In particular the impact of grain boundaries on the transport perpendicular to the grain boundary plane is studied. Fe-doped SrTiO3 bicrystals were used as prototype mixed conductor. Experimental results obtained by optical spectroscopy (chemical diffusion) and electrochemical impedance spectroscopy (electrical transport) are analysed in terms of continuum models. A unified approach based on the use of “chemical capacitors” is briefly explained. For the description of grain boundary, the Schottky model acting on electronic and ionic charge carriers is used
In this study, the electrical conductivity of undoped cerium oxide is evaluated using impedance spec...
Ionic transport in metal oxides is crucial for the functioning of a broad range of different compone...
The emergent properties arising from the interactions of phases including interfacial contributions ...
Hebb-Wagner polarization technique was applied to Fe-doped SrTiO3 single and bicrystals: as far as ...
Mixed oxygen-ion electronic conductors were prepared starting from the well-established solid lectro...
Mixed ionic–electronic conductors are widely used in devices for energy conversion and storage. Grai...
Under electrical bias, mixed ionic conductors such as SrTiO3 are characterized by oxygen vacancy mig...
Understanding the chemical and charge transport properties of grain boundaries (GBs) with high point...
Presented are the physics and chemistry of an important class of grain boundary types in oxide ceram...
Here we show impedance spectroscopy measurements on a bicrystal of the ionically conducting yttria s...
Perovskites and perovskite related materials are materials that are candidates for applications such...
The effect of the electrode material on the high voltage stoichiometry-polarization ("electrocolora...
In this thesis we have derived a new way to analyze the impedance response of mixed conducting mate...
This paper concerns a 3D mathematical model about the mixed ionic–electronic conductivity in solid o...
Oxygen ion conductors with most symmetrical structures such as fluorite- and perovskite-related phas...
In this study, the electrical conductivity of undoped cerium oxide is evaluated using impedance spec...
Ionic transport in metal oxides is crucial for the functioning of a broad range of different compone...
The emergent properties arising from the interactions of phases including interfacial contributions ...
Hebb-Wagner polarization technique was applied to Fe-doped SrTiO3 single and bicrystals: as far as ...
Mixed oxygen-ion electronic conductors were prepared starting from the well-established solid lectro...
Mixed ionic–electronic conductors are widely used in devices for energy conversion and storage. Grai...
Under electrical bias, mixed ionic conductors such as SrTiO3 are characterized by oxygen vacancy mig...
Understanding the chemical and charge transport properties of grain boundaries (GBs) with high point...
Presented are the physics and chemistry of an important class of grain boundary types in oxide ceram...
Here we show impedance spectroscopy measurements on a bicrystal of the ionically conducting yttria s...
Perovskites and perovskite related materials are materials that are candidates for applications such...
The effect of the electrode material on the high voltage stoichiometry-polarization ("electrocolora...
In this thesis we have derived a new way to analyze the impedance response of mixed conducting mate...
This paper concerns a 3D mathematical model about the mixed ionic–electronic conductivity in solid o...
Oxygen ion conductors with most symmetrical structures such as fluorite- and perovskite-related phas...
In this study, the electrical conductivity of undoped cerium oxide is evaluated using impedance spec...
Ionic transport in metal oxides is crucial for the functioning of a broad range of different compone...
The emergent properties arising from the interactions of phases including interfacial contributions ...