The effect of carboxylate position on the structure of a metal organic framework derived from cyclotriveratrylene
- Martin, Adam D.
- Easun, Timothy L.
- Argent, Stephen P.
- Lewis, William
- Blake, Alexander J.
- Schröder, Martin
DOIAbstract
Two cyclotriveratrylene-based ligands H3L1 and H3L2 have been synthesised using microwave heating and used in the formation of 1 [Zn2(L1)(DMA)2(CH3COO)] and 2 [Zn6(L2)4(DMA)6(H2O)5] (DMA = N,N-dimethylacetamide). 1 displays an unusual trigonal paddlewheel node geometry, while Zn(II) paddlewheels are observed in 2. However the stacking of CTV molecules in 1 is replaced by an uncommon molecular capsule structure in 2
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