The macrocyclic ligands 1-(2-aminoethyl)- (L1) and 1-(3-aminopropyl)-1,5,9-triazacyclododecane (L2) have been synthesised from 2,4-dioxo-1,5,9-triazacyclododecane, and the complexes [ZnL1(OClO3)]ClO4 (trigonal bipyramidal) and [NiL2(NCS)2] (octahedral) characterised by X-ray crystallography; L1 and L2 form more stable complexes than do analogues bearing tertiary amino groups on the pendant arms, but allow higher co-ordination numbers
A range of nitrile-functionalised pendant arm derivatives of [9]aneN3, [9]aneN2S, [9]aneNS2, [12]ane...
Copies of author's previously published articles inserted.Bibliography: leaves 176-187.xiii, 187 lea...
The synthesis of C-aryl monosubstituted derivatives of 1,4,7,10-tetraazacyclododecane (cyclen) by me...
A family of new Group 3, Group 13 and early transition metal complexes of the previously described m...
Introduction. Metal complexes of the ligands derived from 1,4,7,10-tetraazacyclododecane (Cyclen) ar...
The synthesis of a novel macrocyclic ligand containing nine potential coordination sites (six nitrog...
Two new quinquedentate pentaazamacrocycles, 7-(2'-pyridylmethyl)-3,7,11,17-tetraazabicyclo-[11.3.1]h...
Palladium(II) and copper(II) complexes [Pd(L1)Cl2], Pd(L3)Cl2], [Cu(L1)Cl2], Cu(L3)Cl2], [Pd(L2)][BF...
Examples of interesting ligands previously requiring lengthy synthetic procedures have been prepared...
The reinvestigation of the synthesis of a series of first row transition metal complexes with the te...
The 12-membered macrocyclic ligand 1-thia-4,7,10-triazacyclododecane ([12]aneN3S) has been synthesis...
The synthesis and characterization of the new tetraazama-crocycle 4(N),10(N)-bis[2-(3-hydroxy-2-oxo-...
Direct alkylation of the N3O2-macrocycle 1,12,15-triaza-3,4 : 9,10-dibenzo-5,8-dioxacycloheptadecane...
Nitrosation of the Cu(II) and Pd(II) complexes of trans-6,13-dimethyl-1,4,8,11-tetraazacyclotetradec...
The use of orthogonally protected cyclam and 1,9-dithia-5,13-diazacyclohexadecane macrocycles, in co...
A range of nitrile-functionalised pendant arm derivatives of [9]aneN3, [9]aneN2S, [9]aneNS2, [12]ane...
Copies of author's previously published articles inserted.Bibliography: leaves 176-187.xiii, 187 lea...
The synthesis of C-aryl monosubstituted derivatives of 1,4,7,10-tetraazacyclododecane (cyclen) by me...
A family of new Group 3, Group 13 and early transition metal complexes of the previously described m...
Introduction. Metal complexes of the ligands derived from 1,4,7,10-tetraazacyclododecane (Cyclen) ar...
The synthesis of a novel macrocyclic ligand containing nine potential coordination sites (six nitrog...
Two new quinquedentate pentaazamacrocycles, 7-(2'-pyridylmethyl)-3,7,11,17-tetraazabicyclo-[11.3.1]h...
Palladium(II) and copper(II) complexes [Pd(L1)Cl2], Pd(L3)Cl2], [Cu(L1)Cl2], Cu(L3)Cl2], [Pd(L2)][BF...
Examples of interesting ligands previously requiring lengthy synthetic procedures have been prepared...
The reinvestigation of the synthesis of a series of first row transition metal complexes with the te...
The 12-membered macrocyclic ligand 1-thia-4,7,10-triazacyclododecane ([12]aneN3S) has been synthesis...
The synthesis and characterization of the new tetraazama-crocycle 4(N),10(N)-bis[2-(3-hydroxy-2-oxo-...
Direct alkylation of the N3O2-macrocycle 1,12,15-triaza-3,4 : 9,10-dibenzo-5,8-dioxacycloheptadecane...
Nitrosation of the Cu(II) and Pd(II) complexes of trans-6,13-dimethyl-1,4,8,11-tetraazacyclotetradec...
The use of orthogonally protected cyclam and 1,9-dithia-5,13-diazacyclohexadecane macrocycles, in co...
A range of nitrile-functionalised pendant arm derivatives of [9]aneN3, [9]aneN2S, [9]aneNS2, [12]ane...
Copies of author's previously published articles inserted.Bibliography: leaves 176-187.xiii, 187 lea...
The synthesis of C-aryl monosubstituted derivatives of 1,4,7,10-tetraazacyclododecane (cyclen) by me...