Treatment of DyCl3(H2O)(6) with thionyl chloride in the presence of tetrahydrofuran provided colourless crystals of DyCl3(THF)(3.5), subsequently identified as the ionic salt [trans-DyCl2(THF)(5)][trans-DyCl4(THF)(2)] by an X-ray diffraction study. The dysprosium atom in the monocation is seven coordinate with the trans-DyCl2 unit [Dy-Cl, 2.624(5) Angstrom] surrounded by five tetrahydrofuran molecules (Dy-O, mean 2.41(2) Angstrom) in a regular pentagonal bipyramidal geometry. For the anion the dysprosium atom is six coordinate with an octahedral geometry comprising four equatorial chlorine atoms (Dy-Cl, mean 2.642(5) Angstrom) and two axial tetrahydrofuran molecules (Dy-O, 2.41(2) Angstrom). Copyright (C) 1996 Elsevier Science Lt
The molar constants of paramagnetic birefringence (PBR) for the dimeric dysprosium(iii)d- and dl-tar...
The molar constants of paramagnetic birefringence (PBR) for the dimeric dysprosium(iii)d- and dl-tar...
The molar constants of paramagnetic birefringence (PBR) for the dimeric dysprosium(iii)d- and dl-tar...
ErCl3(thf)(3.5) has been identified by an X-ray diffraction study as the ionic salt [trans-ErCl2(thf...
Department of Chemistry, University of Warwick, Coventry, CV4 7AL, U.K. Manuscript received 12 Dece...
Treatment of YCl3 . 6H(2)O with thionyl chloride in acetonitrile solution facilitated partial dehydr...
Single crystals of (Ph4P)DyCl4(CH3CN) is obtained from the reaction of dysprosium trichloride, DyCl...
Halide abstraction from a lanthanide(III) chloride using antimony(v) chloride as abstractor provides...
The compound dysprosium(III) 2-metoxybenzoate, {[Dy(2-MeO-Bz)2μ-(2-MeO-Bz)(H2O)2]2·4H2O}n (2-MeO-Bz ...
Department of Chemistry, University of Warwick, Coventry, CV 4 7 AL, UK Department of Chemistry, Uni...
Praseodymium(III), neodymium(III) and gadolinium(III) chloride adducts with tetrahydrofuran (THF) ha...
The crystal structure of the title compound was determined by X-ray diffraction. The dysprosium ion ...
The solution and solid-state structures of a Dy(III) complex with 1,4,7,10-tetraazacyclododecane-1,4...
The crystal structure of the title salt, C8H12N+·Cl−·H2O, consists of di...
Four dysprosium (Dy) single carboxylates, a formate, a propionate, a butyrate and an oxalate have be...
The molar constants of paramagnetic birefringence (PBR) for the dimeric dysprosium(iii)d- and dl-tar...
The molar constants of paramagnetic birefringence (PBR) for the dimeric dysprosium(iii)d- and dl-tar...
The molar constants of paramagnetic birefringence (PBR) for the dimeric dysprosium(iii)d- and dl-tar...
ErCl3(thf)(3.5) has been identified by an X-ray diffraction study as the ionic salt [trans-ErCl2(thf...
Department of Chemistry, University of Warwick, Coventry, CV4 7AL, U.K. Manuscript received 12 Dece...
Treatment of YCl3 . 6H(2)O with thionyl chloride in acetonitrile solution facilitated partial dehydr...
Single crystals of (Ph4P)DyCl4(CH3CN) is obtained from the reaction of dysprosium trichloride, DyCl...
Halide abstraction from a lanthanide(III) chloride using antimony(v) chloride as abstractor provides...
The compound dysprosium(III) 2-metoxybenzoate, {[Dy(2-MeO-Bz)2μ-(2-MeO-Bz)(H2O)2]2·4H2O}n (2-MeO-Bz ...
Department of Chemistry, University of Warwick, Coventry, CV 4 7 AL, UK Department of Chemistry, Uni...
Praseodymium(III), neodymium(III) and gadolinium(III) chloride adducts with tetrahydrofuran (THF) ha...
The crystal structure of the title compound was determined by X-ray diffraction. The dysprosium ion ...
The solution and solid-state structures of a Dy(III) complex with 1,4,7,10-tetraazacyclododecane-1,4...
The crystal structure of the title salt, C8H12N+·Cl−·H2O, consists of di...
Four dysprosium (Dy) single carboxylates, a formate, a propionate, a butyrate and an oxalate have be...
The molar constants of paramagnetic birefringence (PBR) for the dimeric dysprosium(iii)d- and dl-tar...
The molar constants of paramagnetic birefringence (PBR) for the dimeric dysprosium(iii)d- and dl-tar...
The molar constants of paramagnetic birefringence (PBR) for the dimeric dysprosium(iii)d- and dl-tar...