Synthesis of poly(lactide)s with modified thermal and mechanical properties

The use of poly(lactide)-based materials is, in part, limited by their physical and mechanical properties. This article reviews the methods that have been employed to enable enhancement of the materials properties through synthetic manipulation of the polymer structure including block copolymer synthesis and modification of the lactide monomer structure, focusing on the application of ring-opening polymerization. In turn the effect of these structural modifications on the properties of the resultant materials are reported