Poly(vinyl acetate)−Co(acac)2 macroinitiators, prepared by cobalt-mediated radical polymerization of vinyl acetate (VAc), were used to synthesize well-defined poly(vinyl acetate)-b-poly(acrylonitrile) (PVAc-b-PAN) block copolymers. Different solvents and temperatures were tested for the polymerization of the acrylonitrile segment by cobalt-mediated radical polymerization (CMRP), and copolymers with low polydispersity were obtained provided that dimethylformamide was used as solvent at 0 °C. The mechanism of control was assumed to change from a degenerative chain transfer mechanism for the VAc polymerization to a reversible-termination process for the AN polymerization. The hydrolysis of the ester groups of the PVAc block and the nitrile gro...
The cobalt-mediated radical polymerization of vinyl acetate was extended to copolymerization with I-...
Controlled/living radical polymerization (CRP/LRP) provides a versatile route for the synthesis of w...
The successful controlled homopolymerization of acrylonitrile (AN) by cobalt-mediated radical polyme...
Poly(vinyl acetate)¿Co(acac)2 macroinitiators, prepared by cobalt-mediated radical polymerization of...
Well-defined amphiphilic block copolymers of poly(vinyl acetate) (PVAc) and poly(N-vinylpyrrolidone)...
Poly(vinyl acetate) (PVAc) chains of a low polydispersity (Mw/Mn similar to 1.1-1.2) have been prepa...
The synthesis of poly(vinyl acetate)-b-poly(vinyl chloride) (PVAc-b-PVC) block copolymers by Cobalt-...
peer reviewedWell-defined poly(vinyl acetate) macroinitiators, with the chains thus end-capped by a ...
Thermo-responsive block copolymers based on poly(N-vinylcaprolactam) (PNVCL) have been prepared by c...
Controlled radical polymerization (CRP) is a valuable strategy to design a large range of polymers w...
peer reviewedGraft copolymers have been prepared by one-step organometallic-mediated radical polymer...
Recent developments in cobalt-mediated radical polymerization (CMRP) and progress in the mechanistic...
peer reviewedConjugated vinyl lactones commonly serve as precursors of polymers with pendant cyclic ...
peer reviewedPoly(vinyl acetate) (PVAc) chains prepared by cobalt-mediated radical polymerization in...
The use of CO2-based α-alkylidene cyclic carbonates in controlled radical polymerization has so far ...
The cobalt-mediated radical polymerization of vinyl acetate was extended to copolymerization with I-...
Controlled/living radical polymerization (CRP/LRP) provides a versatile route for the synthesis of w...
The successful controlled homopolymerization of acrylonitrile (AN) by cobalt-mediated radical polyme...
Poly(vinyl acetate)¿Co(acac)2 macroinitiators, prepared by cobalt-mediated radical polymerization of...
Well-defined amphiphilic block copolymers of poly(vinyl acetate) (PVAc) and poly(N-vinylpyrrolidone)...
Poly(vinyl acetate) (PVAc) chains of a low polydispersity (Mw/Mn similar to 1.1-1.2) have been prepa...
The synthesis of poly(vinyl acetate)-b-poly(vinyl chloride) (PVAc-b-PVC) block copolymers by Cobalt-...
peer reviewedWell-defined poly(vinyl acetate) macroinitiators, with the chains thus end-capped by a ...
Thermo-responsive block copolymers based on poly(N-vinylcaprolactam) (PNVCL) have been prepared by c...
Controlled radical polymerization (CRP) is a valuable strategy to design a large range of polymers w...
peer reviewedGraft copolymers have been prepared by one-step organometallic-mediated radical polymer...
Recent developments in cobalt-mediated radical polymerization (CMRP) and progress in the mechanistic...
peer reviewedConjugated vinyl lactones commonly serve as precursors of polymers with pendant cyclic ...
peer reviewedPoly(vinyl acetate) (PVAc) chains prepared by cobalt-mediated radical polymerization in...
The use of CO2-based α-alkylidene cyclic carbonates in controlled radical polymerization has so far ...
The cobalt-mediated radical polymerization of vinyl acetate was extended to copolymerization with I-...
Controlled/living radical polymerization (CRP/LRP) provides a versatile route for the synthesis of w...
The successful controlled homopolymerization of acrylonitrile (AN) by cobalt-mediated radical polyme...