L'autoionisation électronique dans le Monoxide de Carbone: les effets du mouvement vibrationnel.
- Leyh, Bernard
- Delwiche, Jacques
- Hubin-Franskin, Marie-Jeanne
- Nenner, I.
DOIAbstract
New continuous measurements of the vibrationally resolved photoionization cross sections of CO+ X2Sigma+ and A2Pi between 63 and 83 nm are reported. We assign the Rydberg series converging to CO+ A2Pi. The effects of the vibrational motion are interpreted on the basis of the Condon approximation. This approximation is shown to allow a qualitative understanding of the decay of the Rydberg series converging to the A2Pi and B2Sigma+ states of CO+
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