In-situ polymerization of monoethylenically unsaturated monomers with secondary amines

publication date: 2004-06-16; filing date: 2003-12-01A process for the preparation of any of well-defined homopolymers, random and block copolymers is disclosed. The process that entails forming a mixture of monomers, a hindered secondary amine and an oxidizing agent is characterized in the absence of any additional free-radical initiator