The Ordovician is known as a period with high temperatures and high sea levels and a cooling event at the end of the period, leading to the Hirnantian glaciation and the !rst of the ‘big !ve’ mass extinctions of marine life. The cause of this cooling event remains unclear. Several authors correlate it with a drop in atmospheric pCO2 to a threshold permitting the ice accumulation on the Gondwana supercontinent. However, what are the reasons of the atmospheric pCO2 decrease? Here, we follow the hypothesis initiated by Barnes (2004) that an Ordovician superplume event occurred during the Middle to Late Ordovician. Such an event would not only have a large impact on the Ordovician biodiversi!cation (Barnes, 2004) but it would also be res...