Maritime networks of coastal and insular countries constitute fundamental transportation systems affecting the economy and the developmental dynamics of their countries. Under this perspective, the present article studies the Greek Maritime transportation Network (GMN), by using a complex network approach for the part of structural analysis and empirical techniques for the socioeconomic evaluation of the GMN’s topology. A methodological framework is developed for dealing with the GMN’s disconnectivity, which is evaluated by the empirical analysis. The curve fitting procedure on the degree distribution data indicated the existence of some scale-free network properties of the GMN, which seemed to be also captured as high correlations between ...