Novel Method for the Fabrication of a Charge-Transfer Complex Crystal by Photoirradiation
- Matsuda, Masaki
- Nishi, Miki
- Koga, Shoko
- Fujishima, Mika
- Hoshino, Norihisa
- Akutagawa, Tomoyuki
- Hasegawa, Hiroyuki
- マツダ, マサキ
- ニシ, ミキ
- コガ, ショウコ
- フジシマ, ミカ
- ホシノ, ノリヒサ
- アクタガワ, トモユキ
- ハセガワ, ヒロユキ
- 松田, 真生
- 西, 美樹
- 古賀, 翔子
- 藤嶋, 美加
- 星野, 哲久
- 芥川, 智行
- 長谷川, 裕之
Publication date
July 2014
DOI Publisher
Wiley ISSN
0947-6539 Citation count (estimate)
3Abstract
A novel method for the fabrication of a charge-transfer complex crystal was developed. Photoirradiation of a solution of TPP[Co(tbp)(CN)2] and TPP[Co(Pc)(CN)2] (tbp=tetrabenzoporphyrin, Pc=phthalocyanine, TPP=tetraphenylphosphonium) gave a molecular conducting crystal of a charge-transfer complex TPP[Co(tbp)(CN)2]2, which was produced by the process in which the photoexcited electron in tbp was transferred from the LUMO of tbp to that of Pc
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