Constructing CrIII-centered heterometallic complexes: [NiII6CrIII] and [CoII6CrIII] wheels
- Kakaroni, Foteini E.
- Collet, Alexandra
- Sakellari, Eirini
- Tzimopoulos, Demetrios
- Siczek, Milosz
- Lis, Tadeusz
- Murrie, Mark
- Milios, Constantinos J.
Publication date
January 2018
DOI Publisher
Royal Society of Chemistry (RSC) ISSN
1477-9226 Language
EnglishAbstract
The solvothermal reaction between Cr(acac)3, MCl2.6H2O (M= Ni, Co) and 2-hydroxy-4-methyl-6-phenyl-pyridine-3-amidoxime (H2L), under basic conditions, led to the synthesis of the heterometallic heptanuclear clusters [MII6Cr(HLzw)6(HL)6].3Cl (M= Ni, 1; Co, 2), with the nickel analogue displaying an S= 9/2 spin ground-state
Add to ORKG