A Nanocomposite Based on a Styrene-Acrylate Copolymer and Organically Modified Montmorillonite. 1. Mechanical Properties

The preparation of polymer nanocomposites by mixing a solution of a styrene-acrylate copolymer with a suspension of organically modified montmorillonite in dimethyl formamide is described. Seven different compositions with organomontmorillonite content from 0 to 7 wt.% were prepared and tested. Results of their X-ray diffraction analysis are presented. Data on the influence of organomontmorillonite content on the tensile stress-strain curves, elastic modulus, strength, and ultimate elongation of the nanocomposites are obtained. The concentration dependences of elastic properties of materials with differently oriented platelike nanoparticles is analyzed by using an algorithm elaborated for stepwise calculations of elastic constants with account of the features of structural hierarchy of intercalated and exfoliated nanocomposites