Pincer-Supported Carbonyl Complexes of Cobalt(I)
- Guard, Lousie M
- Hebden, Travis J
- Linn, Donald Edward, Jr
- Heinekey, D M
Publication date
January 2017
DOI Publisher
Opus: Research \u26 Creativity at IPFW ISSN
0276-7333Abstract
A pair of POCOP-supported mono- and dicarbonyl complexes of Co have been prepared and crystallographically characterized. The reactivity of (tBuPOCOP)Co(CO) with H2, acids, and carbon monoxide has been compared to that of the previously reported Rh and Ir counterparts. Co is found to share reactivity traits with both Rh and Ir
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