Palladium-Catalyzed Enantioselective Conjugate Addition of Arylboronic Acids

Gini, Francesca,
Hessen, Bart,
Minnaard, Adriaan J.,

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Publication date

January 2005

DOI

10.1021/ol052222d

ISSN

1523-7060

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Abstract

The first asymmetric palladium-catalyzed conjugate addition of arylboronic acids to α,β-unsaturated aldehydes, ketones, and esters is described. For cyclic substrates, excellent chemo-, regio-, and enantioselectivities are achieved when a Pd(O2CCF3)2/DuPHOS catalyst is applied.

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Palladium-Catalyzed Enantioselective Conjugate Addition of Arylboronic Acids

Abstract

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Palladium-Catalyzed Enantioselective Conjugate Addition of Arylboronic Acids

Abstract

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