Two chiral nonracemic γ-amino alcohols, ephedrine thiol and the corresponding (thio)-phosphoramidates and (thio)-phosphinamides have been examined as catalysts for the reduction of propiophenone by various boranes. Up to 95% e.e. can be obtained with the phosphorus derivatives.
We have designed and prepared a catalyst for the asymmetric reduction of ketones which combines a ph...
The novel chiral phosphoramide, 1,4-bis[(5S)-1,3-diaza-2-phospha-2-oxo-3-phenylbicyclo(3.3.0)octan-2...
The asymmetric borane reduction of prochiral ketones with a series of easily constructed chiral C-3-...
Two chiral nonracemic γ-amino alcohols, ephedrine thiol and the corresponding (thio)-phosphoramidate...
Two chiral nonracemic γ-amino alcohols, ephedrine thiol and the corresponding (thio)-phosphoramidate...
Two chiral nonracemic γ-amino alcohols, ephedrine thiol and the corresponding (thio)-phosphoramidate...
Two chiral nonracemic γ-amino alcohols, ephedrine thiol and the corresponding (thio)-phosphoramidate...
Two chiral nonracemic γ-amino alcohols, ephedrine thiol and the corresponding (thio)-phosphoramidate...
Synthesis of several new chiral phosphinamide catalysts with a proximal hydroxyl group from L-serine...
We have identified a new class of catalysts for the asymmetric reduction of prochiral ketones by bor...
Representative chiral catalysts containing the N---P=O structural framework having (5S)-1,3-diaza-2-...
A novel class of recoverable and highly stable phosphinamide catalysts for the asymmetric reduction ...
A series of chiral bifunctional squaric prolinol ligands, having N, S substituents at C(3) of the sq...
A series of new chiral C-3-symmetric tris(beta-hydroxy phosphoramide) ligands have been synthesized ...
The work described in the thesis has two objectives. The first is to prepare P(V) compounds, mainly ...
We have designed and prepared a catalyst for the asymmetric reduction of ketones which combines a ph...
The novel chiral phosphoramide, 1,4-bis[(5S)-1,3-diaza-2-phospha-2-oxo-3-phenylbicyclo(3.3.0)octan-2...
The asymmetric borane reduction of prochiral ketones with a series of easily constructed chiral C-3-...
Two chiral nonracemic γ-amino alcohols, ephedrine thiol and the corresponding (thio)-phosphoramidate...
Two chiral nonracemic γ-amino alcohols, ephedrine thiol and the corresponding (thio)-phosphoramidate...
Two chiral nonracemic γ-amino alcohols, ephedrine thiol and the corresponding (thio)-phosphoramidate...
Two chiral nonracemic γ-amino alcohols, ephedrine thiol and the corresponding (thio)-phosphoramidate...
Two chiral nonracemic γ-amino alcohols, ephedrine thiol and the corresponding (thio)-phosphoramidate...
Synthesis of several new chiral phosphinamide catalysts with a proximal hydroxyl group from L-serine...
We have identified a new class of catalysts for the asymmetric reduction of prochiral ketones by bor...
Representative chiral catalysts containing the N---P=O structural framework having (5S)-1,3-diaza-2-...
A novel class of recoverable and highly stable phosphinamide catalysts for the asymmetric reduction ...
A series of chiral bifunctional squaric prolinol ligands, having N, S substituents at C(3) of the sq...
A series of new chiral C-3-symmetric tris(beta-hydroxy phosphoramide) ligands have been synthesized ...
The work described in the thesis has two objectives. The first is to prepare P(V) compounds, mainly ...
We have designed and prepared a catalyst for the asymmetric reduction of ketones which combines a ph...
The novel chiral phosphoramide, 1,4-bis[(5S)-1,3-diaza-2-phospha-2-oxo-3-phenylbicyclo(3.3.0)octan-2...
The asymmetric borane reduction of prochiral ketones with a series of easily constructed chiral C-3-...