High Efficiency And Enantioselectivity In The Rh-catalyzed Conjugate Addition Of Arylboronic Acids Using Monodentate Phosphoramidites
- Feringa, B.L.,
- Boiteau, J.G.,
- Minnaard, A.J.,
DOIAbstract
A very fast reaction and enantioselectivities >98% have been reached in the rhodium-catalyzed arylbor-onic acid addition to enones using a monodentate phos-phoramidite ligand. Temperature-dependent studies show that monodentate phosphoramidites form stable complexes with metals and can induce high enantioselectivities even at high temperatures in polar solvents.
Add to ORKG