Structural reassignment of Cytosporolides A - C via biomimetic synthetic studies and reinterpretation of NMR data

Spence, J.
George, J.

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Publication date

January 2011

DOI

10.1021/ol202181g

Publisher

American Chemical Society (ACS)

ISSN

1523-7060

Journal

Organic Letters

Citation count (estimate)

Abstract

A structure revision for the recently isolated fungal meroterpenoids, cytosporolides A-C, is suggested based on biosynthetic speculation and reinterpretation of existing spectroscopic data. The structure revision is supported by a biomimetic synthetic study, featuring a [4 + 2] cycloaddition reaction between a presumed o-quinone methide intermediate and β-caryophyllene.Justin T. J. Spence and Jonathan H. Georg

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Structural reassignment of Cytosporolides A - C via biomimetic synthetic studies and reinterpretation of NMR data

Abstract

Extracted data

Structural reassignment of Cytosporolides A - C via biomimetic synthetic studies and reinterpretation of NMR data

Abstract

Extracted data

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