Reversible Sm(III)/Sm(II) redox chemistry of an organosamarium(III) complex
- Wang, Jun
- Amos, Ruth I. J.
- Frey, Alistair S. P.
- Gardiner, Michael G.
- Cole, Marcus Lawford
- Junk, Peter C.
Publication date
January 2005
DOI Publisher
American Chemical Society (ACS) ISSN
0276-7333 Journal
Organometallics Citation count (estimate)
16Abstract
Copyright © 2005 American Chemical SocietyA binuclear samarium(III) complex featuring the -1:1-bound dianion of 1,4-di-tert-butyl-1,4-diazabuta-1,3-diene has been prepared which exhibits reversible redox behavior, reverting to the samarium(II) precursor when dissolved in tetrahydrofuran. The new samarium(III) complex has been characterized by 1H and 13C NMR spectral data, microanalytical data, magnetic moment measurements in solution, and an X-ray crystal structure determination.Jun Wang, Ruth I. J. Amos, Alistair S. P. Frey, and Michael G. Gardiner, Marcus L. Cole and Peter C. Jun
Add to ORKG