Thermoelectric Generators

A thermoelectric generator is a solid-state device that converts a heat flux into electri-cal power via the Seebeck effect. When a thermoelectric generator is inserted between a solar-absorbing surface and a heat sink, a solar thermoelectric generator is created which converts sunlight into electrical power. This thesis describes the design and optimization of solar thermoelectric generators, with a focus on systems with high optical concentration which utilize multiple material systems to maximize efficiency over a large temperature difference. Both single-stage and cascaded (multi-stage) generators are considered, over an optical concentration range of 0.1 to 1000X. It is shown that for high-concentration Bi2Te3/skutterudite solar thermoelectric gen-erators, conversion efficiencies of 13 % are possible with current thermoelectric ma-terials and selective surfaces. Better selective surfaces are needed to improve the efficiency of solar thermoelectric generators. In this thesis, ideal selective surfaces for solar thermoelectric generators are characterized. Non-ideal selective surfaces are also characterized, with emphasis on how the non-idealities affect the solar thermo