Add to ORKGConditions are described for converting a chlorocyclopropane with a CHCO2R group in the ring to the corresponding methoxycyclopropane in excellent yield. The non-reactivity of a chlorocyclopropane lacking a CHCO2R group in the ring indicated that the successful reactions proceed via cyclopropenes. Keywords: Cyclopropanes; Cyclopropenes; Elimination-Addition Reactions; Nucleophilic Substitution
Gustavson has reported that the photochemical chlorination of cyclopropane gave 1, 1-dichlorocyclopr...
Transition metal-catalyzed cycloadditions of cyclopropanes have been well developed over the past se...
Cyclopropanation of alkenes is a well-established textbook reaction for the synthesis of cyclopropan...
The interest in cyclopropane derivatives is caused by the facts that, first, the three-carbon ring i...
The cyclopropane moiety is found in a wide variety of the natural products, from small amino acid mo...
Triscycloproparenes 1 and 2 were synthesized by treating the Diels-Alder adducts of 1-bromo-2-chloro...
The cyclopropane moiety is found in a wide variety of the natural products, from small amino acid mo...
On treatment with Bu4N+ F-, cyclopropanecarboxylates I (R = Cl; R1 = Cl, F; R2 = OCMe3) undergo Cl-F...
Abstract: The versatile cyclopropene synthon 1-bromo-2-chlorocyclopropene has been used to synthesiz...
Copyright © 2011 Anatolii N. Vereshchagin et al. This is an open access article distributed under th...
International audience(Chemical Equation Presented) Cyclopropylacyl radicals derived from S-cyclopro...
Methylenecyclopropene was generated under two different reaction conditions. The passage of 2-chloro...
Master's thesis in Biological ChemistryThe main purpose of this thesis was to study ring-openings of...
International audienceWith the goal of accessing yet unknown SF5-cyclopropyl building blocks, the ra...
1-Bromo-2-chlorocyclopropene (BCC) was prepared by treating 1-bromo-2,2-dichlorocyclopropyltrimethyl...
Gustavson has reported that the photochemical chlorination of cyclopropane gave 1, 1-dichlorocyclopr...
Transition metal-catalyzed cycloadditions of cyclopropanes have been well developed over the past se...
Cyclopropanation of alkenes is a well-established textbook reaction for the synthesis of cyclopropan...
The interest in cyclopropane derivatives is caused by the facts that, first, the three-carbon ring i...
The cyclopropane moiety is found in a wide variety of the natural products, from small amino acid mo...
Triscycloproparenes 1 and 2 were synthesized by treating the Diels-Alder adducts of 1-bromo-2-chloro...
The cyclopropane moiety is found in a wide variety of the natural products, from small amino acid mo...
On treatment with Bu4N+ F-, cyclopropanecarboxylates I (R = Cl; R1 = Cl, F; R2 = OCMe3) undergo Cl-F...
Abstract: The versatile cyclopropene synthon 1-bromo-2-chlorocyclopropene has been used to synthesiz...
Copyright © 2011 Anatolii N. Vereshchagin et al. This is an open access article distributed under th...
International audience(Chemical Equation Presented) Cyclopropylacyl radicals derived from S-cyclopro...
Methylenecyclopropene was generated under two different reaction conditions. The passage of 2-chloro...
Master's thesis in Biological ChemistryThe main purpose of this thesis was to study ring-openings of...
International audienceWith the goal of accessing yet unknown SF5-cyclopropyl building blocks, the ra...
1-Bromo-2-chlorocyclopropene (BCC) was prepared by treating 1-bromo-2,2-dichlorocyclopropyltrimethyl...
Gustavson has reported that the photochemical chlorination of cyclopropane gave 1, 1-dichlorocyclopr...
Transition metal-catalyzed cycloadditions of cyclopropanes have been well developed over the past se...
Cyclopropanation of alkenes is a well-established textbook reaction for the synthesis of cyclopropan...