Add to ORKGUsing 1H- and 13C-NMR spectroscopies, cationic intermediates formed by activation of L2ZrCl2 with methylaluminoxane (MAO) in toluene were monitored at Al/Zr ratios from 50 to 1000 (L2 are various cyclopentadienyl (Cp), indenyl (Ind) and fluorenyl (Flu
The products obtained with the system {[(ArN=C(Me))2C5H3N]FeCl2}/MAO (Ar = 2-C6H4(Et)) (1) and the o...
The solution structure of the zwitterionic complex [Zr(p-CH(2)C(6)H(4)CMe(3))(3)[B(C6F5)(3)(p-CH(2)C...
Ethylene polymerization by zirconocene-B(C6F5)(3) catalysts with various aluminum compounds has been...
Using 1H- and 13C-NMR spectroscopies, cationic intermediates formed by activation of L2ZrCl2 with me...
The growth of polyolefin chains in zirconocene-based catalyst systems is generally agreed to occur b...
The structures of intermediates formed upon the activation by methylaluminoxane (MAO) of a wide rang...
1H and 13C NMR studies of the reactions between two β-alkyl-substituted aluminoxanes obtained from t...
Reactive species in SiO2-supported, zirconocene-based olefin-polymerization catalysts have been char...
Addition of 1-hexene to methylalumoxane-activated catalyst systems based on rac-Me(2)Si(ind)(2)ZrMe(...
The reaction of (bpzmp)Zr(CH2Ph)3 with B(C6F5)3 produces the active ethylene polymerisation catalyst...
13C NMR analysis of poly(4-methyl-1,3-pentadiene) (poly(4-MPD)) obtained by using the C2symmetric zi...
The reactions of Cp*Zr(CH3)(3), 1, and Cp2Zr(CH3)(2), 2, with partially dehydroxylated silica, silic...
A dinuclear zirconium complex, (η^5:η^5-Fulvalene)[(η^5-C_5H_5)Zr(μ-Cl)]_2 (2), was synthesized from...
The products obtained with the system {[(ArN=C(Me))2C5H3N]FeCl2}/MAO (Ar = 2-C6H4(Et)) (1) and the o...
The solution structure of the zwitterionic complex [Zr(p-CH(2)C(6)H(4)CMe(3))(3)[B(C6F5)(3)(p-CH(2)C...
Ethylene polymerization by zirconocene-B(C6F5)(3) catalysts with various aluminum compounds has been...
Using 1H- and 13C-NMR spectroscopies, cationic intermediates formed by activation of L2ZrCl2 with me...
The growth of polyolefin chains in zirconocene-based catalyst systems is generally agreed to occur b...
The structures of intermediates formed upon the activation by methylaluminoxane (MAO) of a wide rang...
1H and 13C NMR studies of the reactions between two β-alkyl-substituted aluminoxanes obtained from t...
Reactive species in SiO2-supported, zirconocene-based olefin-polymerization catalysts have been char...
Addition of 1-hexene to methylalumoxane-activated catalyst systems based on rac-Me(2)Si(ind)(2)ZrMe(...
The reaction of (bpzmp)Zr(CH2Ph)3 with B(C6F5)3 produces the active ethylene polymerisation catalyst...
13C NMR analysis of poly(4-methyl-1,3-pentadiene) (poly(4-MPD)) obtained by using the C2symmetric zi...
The reactions of Cp*Zr(CH3)(3), 1, and Cp2Zr(CH3)(2), 2, with partially dehydroxylated silica, silic...
A dinuclear zirconium complex, (η^5:η^5-Fulvalene)[(η^5-C_5H_5)Zr(μ-Cl)]_2 (2), was synthesized from...
The products obtained with the system {[(ArN=C(Me))2C5H3N]FeCl2}/MAO (Ar = 2-C6H4(Et)) (1) and the o...
The solution structure of the zwitterionic complex [Zr(p-CH(2)C(6)H(4)CMe(3))(3)[B(C6F5)(3)(p-CH(2)C...
Ethylene polymerization by zirconocene-B(C6F5)(3) catalysts with various aluminum compounds has been...