Spectra and Dynamics of Calcium Monochloride

The alkaline earth monohalides (MX) represent an ideal molecule for studying molecu-lar Rydberg states, as they are well described as by an ion-core containing two closed shell atomic ions (M2+,X−) and an unpaired electron. The spectra and dynamics of Rydberg states allows the testing of theories of electronic structure and nuclear-electronic energy exchange. This thesis presents the results of a series of experimental studies on the least well-studied MX molecule, CaCl (calcium monochloride). The majority of these investigations were conducted in a specialized molecular beam ap-paratus described in some detail. The spectroscopy of CaCl is challenging because of the onset of predissociation at n * ∼ 3. The reduction in ionization quantum yield associated with the predissociation greatly reduces our ability to record Rydberg state spectra, but provides opportunities to model the predissociation processes with the results of observed states. Such a model was accomplished with the 2Σ+ repulsive state via a linewidth analysis, and with the 2Π state with a qualitative model