ABSTRACT A new compound [CpCo(Se2C2B10H9)CH2C(O)C4H3O] has been synthesized and characterized by elemental analysis, IR spectroscopy, NMR, MS and single-crystal X-ray diffraction. The complex crystallizes in the monoclinic system, space group P21/c with a = 10.9481(10), b = 24.6600(12), c = 25.7430(14) Å, β = 100.863(3)º, C42H57B30Co3O6Se6·CH2Cl2·0.25H2O, Mr = 1722.16, V = 6825.6(8) Å3, Dc = 1.676 g/cm3, Z = 1 and F(000) = 3346. The molecular structure shows a 1:1 ratio product of the two reactants of 16e half-sandwich complex CpCo(Se2C2B10H10) and alkyne 1-(2-furyl)-2-propyn-1-one. The hydrogen atom in the B(3) position of CpCo(Se2C2B10H10) has been activated and migrated to the terminal carbon of 1-(2-furyl)-2-propyn-1-one to form the B−...
R factor = 0.045; wR factor = 0.133; data-to-parameter ratio = 16.4. The furan ring in the title com...
International audienceSynopsis The crystal structure of 2-hydroxy-3-methoxyphenyl-(bis(benzylthio))m...
Abstract: 1,3-Dicarbonyl compounds were synthesized by the reaction of 9,10-phenanthrenequinone with...
In the title compound, C12H9NO3, the benzoate and furan rings are almost coplanar, making a dihedral...
The title compound, C17H18O2, crystallizes in two-dimensional sheets, in which the 2-(pentyloxy)dibe...
The reactions of the 16e half-sandwich complex CpCoS<sub>2</sub>C<sub>2</sub>B<sub>10</sub>H<sub>10<...
The title compound, C5H4ClNOSe, is the product of the reaction of sulfuryl chloride and 2-selanyl-1-...
由CS_2,n_2H_4和C_4H_3OCHO合成C_(11)H_(10)n_4O_2S·1/2dMf,M_r=298.79,橙黄针状晶体,三斜晶系,空间群P1,A=8.912(3),b=9.989(...
The synthesis and crystal structure of the title compound, C28H28O2, are reported. The C=C—C—C torsi...
In the title compound, C24H17NO2, the carbonyl O atom of the benzoyl group is cis with respect to th...
R factor = 0.032; wR factor = 0.085; data-to-parameter ratio = 9.4. In the molecule of the title com...
The title compound, C22H34O6, is a product of oxidation of squalene with the catalytic system RuO4(c...
The title compound, C16H22O2, was synthesized in order to obtain its guest-free form because `wheel-...
In the title compound, C\sb 14H\sb 11Cl\sb 2NO\sb 4, the dihedral angle between the two aromatic rin...
In the title compound, C13H14O5, the furan ring is essentially planar [maximum deviation = 0.031 (3)...
R factor = 0.045; wR factor = 0.133; data-to-parameter ratio = 16.4. The furan ring in the title com...
International audienceSynopsis The crystal structure of 2-hydroxy-3-methoxyphenyl-(bis(benzylthio))m...
Abstract: 1,3-Dicarbonyl compounds were synthesized by the reaction of 9,10-phenanthrenequinone with...
In the title compound, C12H9NO3, the benzoate and furan rings are almost coplanar, making a dihedral...
The title compound, C17H18O2, crystallizes in two-dimensional sheets, in which the 2-(pentyloxy)dibe...
The reactions of the 16e half-sandwich complex CpCoS<sub>2</sub>C<sub>2</sub>B<sub>10</sub>H<sub>10<...
The title compound, C5H4ClNOSe, is the product of the reaction of sulfuryl chloride and 2-selanyl-1-...
由CS_2,n_2H_4和C_4H_3OCHO合成C_(11)H_(10)n_4O_2S·1/2dMf,M_r=298.79,橙黄针状晶体,三斜晶系,空间群P1,A=8.912(3),b=9.989(...
The synthesis and crystal structure of the title compound, C28H28O2, are reported. The C=C—C—C torsi...
In the title compound, C24H17NO2, the carbonyl O atom of the benzoyl group is cis with respect to th...
R factor = 0.032; wR factor = 0.085; data-to-parameter ratio = 9.4. In the molecule of the title com...
The title compound, C22H34O6, is a product of oxidation of squalene with the catalytic system RuO4(c...
The title compound, C16H22O2, was synthesized in order to obtain its guest-free form because `wheel-...
In the title compound, C\sb 14H\sb 11Cl\sb 2NO\sb 4, the dihedral angle between the two aromatic rin...
In the title compound, C13H14O5, the furan ring is essentially planar [maximum deviation = 0.031 (3)...
R factor = 0.045; wR factor = 0.133; data-to-parameter ratio = 16.4. The furan ring in the title com...
International audienceSynopsis The crystal structure of 2-hydroxy-3-methoxyphenyl-(bis(benzylthio))m...
Abstract: 1,3-Dicarbonyl compounds were synthesized by the reaction of 9,10-phenanthrenequinone with...