Add to ORKGAbstract: Three new ruthenium amidinate complexes were prepared: tris(diisopropylacetamidinato)-ruthenium(III), Ru(iPrNC(Me)NiPr)3 4; bis(diisopropyl-acetamidinato)ruthenium(II) dicarbonyl, Ru( iPrNC(Me)NiPr)2(CO)2 5; and bis(di-tert-butylacetamidinato)ruthenium(II) dicarbonyl, Ru(tBuNC(Me)NtBu)2(CO)2 6. They have been synthesized and charac-terized by 1H NMR, TG and X-ray structure analysis. These three complexes were found to be monomeric and air stable. Compound 6 was found to have sufficient volatility and thermal stability for use in chemical vapor deposition (CVD) and atomic layer deposition (ALD) of ruthenium metal films
In this project, [Cp*RuCl2]2 has been used as the starting material to prepare two new Ruthenium com...
[[abstract]]Reaction of Ru-3(CO)(12) with 6 eq. of beta-diketone ligands (hfac) H, (tmhd) H, (acac) ...
Reaction of 2-(phenylazo)pyridine (pap) with [Ru(PPh3)3X2] (X = Cl, Br) in dichloromethane solution ...
[[abstract]]The deposition of pure ruthenium thin films is reported from carbonyl β-diketonate precu...
[[abstract]]The synthesis and characterization of ruthenium complexes [Ru(CO)(2)(amak)(2)] and [Ru(C...
A series of ruthenium complexes of the general type Ru(CO)2(P(n-Bu)3)2(O2CR)2 (4a, R = Me; 4b, R = E...
The first organoruthenium amidinates bearing a Ru-C σ bond were prepared, and their structures were ...
The synthesis and characterization of RuIII metal complexes [Ru(keim1)3] (1) and [Ru(keim2)3] (2) ar...
textWith the growing demand for miniaturization of devices and for new materials with useful propert...
[[abstract]]A series of organometallic complexes of the general formula [M(CO).sub.2 L.sub.2 ] was p...
[[abstract]]The synthesis and characterization of Ru-III metal complexes [Ru(keim1)(3)] (1) and [Ru(...
(Article begins on next page) The Harvard community has made this article openly available. Please s...
Amide functionalized bipyridine ligands and their ruthenium(II) complexes of the type [Ru(bipyridine...
Journal Article,New and improved routes for the preparation of ruthenium complexes are described. [R...
The ruthenium phosphite hydride complexes H2Ru(P(OR)(3))(4) (R = Me (1), Et (2), Pr-i (3)) were used...
In this project, [Cp*RuCl2]2 has been used as the starting material to prepare two new Ruthenium com...
[[abstract]]Reaction of Ru-3(CO)(12) with 6 eq. of beta-diketone ligands (hfac) H, (tmhd) H, (acac) ...
Reaction of 2-(phenylazo)pyridine (pap) with [Ru(PPh3)3X2] (X = Cl, Br) in dichloromethane solution ...
[[abstract]]The deposition of pure ruthenium thin films is reported from carbonyl β-diketonate precu...
[[abstract]]The synthesis and characterization of ruthenium complexes [Ru(CO)(2)(amak)(2)] and [Ru(C...
A series of ruthenium complexes of the general type Ru(CO)2(P(n-Bu)3)2(O2CR)2 (4a, R = Me; 4b, R = E...
The first organoruthenium amidinates bearing a Ru-C σ bond were prepared, and their structures were ...
The synthesis and characterization of RuIII metal complexes [Ru(keim1)3] (1) and [Ru(keim2)3] (2) ar...
textWith the growing demand for miniaturization of devices and for new materials with useful propert...
[[abstract]]A series of organometallic complexes of the general formula [M(CO).sub.2 L.sub.2 ] was p...
[[abstract]]The synthesis and characterization of Ru-III metal complexes [Ru(keim1)(3)] (1) and [Ru(...
(Article begins on next page) The Harvard community has made this article openly available. Please s...
Amide functionalized bipyridine ligands and their ruthenium(II) complexes of the type [Ru(bipyridine...
Journal Article,New and improved routes for the preparation of ruthenium complexes are described. [R...
The ruthenium phosphite hydride complexes H2Ru(P(OR)(3))(4) (R = Me (1), Et (2), Pr-i (3)) were used...
In this project, [Cp*RuCl2]2 has been used as the starting material to prepare two new Ruthenium com...
[[abstract]]Reaction of Ru-3(CO)(12) with 6 eq. of beta-diketone ligands (hfac) H, (tmhd) H, (acac) ...
Reaction of 2-(phenylazo)pyridine (pap) with [Ru(PPh3)3X2] (X = Cl, Br) in dichloromethane solution ...