Add to ORKGAbstract: Calix [4] pyrrole derivative was used to target lanthanide cations. Meso tetramethyl-tetrakis-[(4-N, N-diethylacetamide) phenoxymethyl] calix [4] pyrrole, L2 was synthesised. This receptor constituted of hard donor atoms at the lower rim which interact with lanthanide cations being hard cations. 1 H NMR investigations showed that both, the pyrrolic N and the acetamide arm group provide sites for interaction with lanthanide metal cations. These findings are verified by conductance measurements in acetonitrile, plots of molar conductance against the ligand/metal cation ratio reveal the formation of 1:2 complexes between this ligand with lanthanide metal cations. Standard thermodynamics parameters of complexation (log Ks, ∆H ᵒ c, ∆
The use of calixpyrroles as cation monitoring systems is very limited. The importance of fundamental...
A ditopic ion-pair receptor (1), which has tunable cation- and anion-binding sites, has been synthes...
Lanthanide cation binding by tetraketone derivatives of p-tert-butyldihomooxacalix[4] arene (methyl...
This thesis investigates the complexing properties of synthetic macrocyclic ligands such as calix[4]...
Following the synthesis and characterization of meso-tetramethyl tetrakis (4-phenoxy acetone) calix[...
The lanthanide and Th4+ complexes with calix[4]arene ligands substituted either on the narrow or at ...
Following an introduction on calixarene chemistry and their metal-ion complexes including some of th...
Following an introduction on the history of Supramolecular Chemistry, the nomenclature, the function...
The synthesis of calix[4]arene derivatives, 5,11,17,23-tetra-tert-butyl[25,27-bis(hydroxy)-26,28-bis...
This thesis concerns the synthesis, characterisation and binding properties of partially substituted...
A new calix[4]pyrrole-based macrocycle, meso-tetramethyl-tetrakis{4-[2-(ethylthio)ethoxy]phenyl}cali...
The binding of lanthanide cations by 2-pyridylmethoxy derivatives ofp-tert-butyldihomooxacalix[4]are...
International audienceLanthanide cation binding by tetraketone derivatives of p-tert-butyldihomooxac...
textThis dissertation reports on the recent discovery that calix[4]pyrrole not only functions as an ...
The complexation ability of a partially substituted lower rim calix[4]arene hydroxyamide derivative,...
The use of calixpyrroles as cation monitoring systems is very limited. The importance of fundamental...
A ditopic ion-pair receptor (1), which has tunable cation- and anion-binding sites, has been synthes...
Lanthanide cation binding by tetraketone derivatives of p-tert-butyldihomooxacalix[4] arene (methyl...
This thesis investigates the complexing properties of synthetic macrocyclic ligands such as calix[4]...
Following the synthesis and characterization of meso-tetramethyl tetrakis (4-phenoxy acetone) calix[...
The lanthanide and Th4+ complexes with calix[4]arene ligands substituted either on the narrow or at ...
Following an introduction on calixarene chemistry and their metal-ion complexes including some of th...
Following an introduction on the history of Supramolecular Chemistry, the nomenclature, the function...
The synthesis of calix[4]arene derivatives, 5,11,17,23-tetra-tert-butyl[25,27-bis(hydroxy)-26,28-bis...
This thesis concerns the synthesis, characterisation and binding properties of partially substituted...
A new calix[4]pyrrole-based macrocycle, meso-tetramethyl-tetrakis{4-[2-(ethylthio)ethoxy]phenyl}cali...
The binding of lanthanide cations by 2-pyridylmethoxy derivatives ofp-tert-butyldihomooxacalix[4]are...
International audienceLanthanide cation binding by tetraketone derivatives of p-tert-butyldihomooxac...
textThis dissertation reports on the recent discovery that calix[4]pyrrole not only functions as an ...
The complexation ability of a partially substituted lower rim calix[4]arene hydroxyamide derivative,...
The use of calixpyrroles as cation monitoring systems is very limited. The importance of fundamental...
A ditopic ion-pair receptor (1), which has tunable cation- and anion-binding sites, has been synthes...
Lanthanide cation binding by tetraketone derivatives of p-tert-butyldihomooxacalix[4] arene (methyl...