ABSTRACT. The complex cis-[ReOBr2(msa)(PPh3)](1) was prepared from trans-[ReOBr3(PPh3)2] and 2-(1-iminoethyl)phenol (Hmsa) in acetonitrile. An X-ray crystallographic study shows that the two bromides are coordinated cis to each other in the equatorial plane cis to the oxo group. DFT calculations on 1 and its trans isomer show that the energy difference between the HOMO and LUMO in the cis isomer is smaller than that in the trans
The reaction of the double Schiff bases, RL, formed from 2,6-diformyl-4-methyl-phenol and p-RC6H4NH2...
The oxo-bridged dinuclear complex [(μ-O){ReO(sal2hpn)} 2].EtOH was prepared by the reaction of trans...
Trans-ReOCl3(PPh3)(2) reacts with 2,3- and 2,6-dihydroxybenzoic acid (H(2)dhb) in an equimolar ratio...
The complex cis-[ReOBr2(msa)(PPh3)](1) was prepared from trans-[ReOBr3(PPh3)2] and 2-(1-iminoethyl)p...
Rhenium(V) complexes containing the [ReX(PPh3)2] 4+ (X = Br, I) moiety were studied. The reaction of...
Crystals of the title compound, fac,cis-[ReBr(C21H21P)2(CO)3], were obtained by recrystallization of...
The crystal and molecular structures of the two bis(amine) complexes of rhenium(I), [ReBr(CO) 3(NHR ...
Rhenium(V) complexes containing the [ReX(PPh3)2]4+ (X = Br, I) moiety were studied. The reaction of ...
The complex cis-[ReO2(Hdab)(py)(2)] (1) (H(2)dab = 1,2-diaminobenzene) has been prepared by reacting...
The complex cis-[ReO2(Hdab)(py)(2)] (1) (H(2)dab = 1,2-diaminobenzene) has been prepared by reacting...
disorder in main residue; R factor = 0.032; wR factor = 0.086; data-to-parameter ratio = 19.9. In th...
In the title salt, (C8H20N)[ReBr(C7H5O2)(CO)3], the ReI atom is octahedrally surrounded by three fac...
[ReBr(CO)5] reacted with phosphinite or phosphonite ligands in benzene or toluene to yield fac-(1) o...
The structure of the title compound, [Re2Cl6(C3H7NO2)2]·1.5H2O, comprises a dinuclear complex cation...
Ruthenium(VI) complexes with a sterically bulky bidentate Schiff base ligand, 2-[(2,6-diisopropylphe...
The reaction of the double Schiff bases, RL, formed from 2,6-diformyl-4-methyl-phenol and p-RC6H4NH2...
The oxo-bridged dinuclear complex [(μ-O){ReO(sal2hpn)} 2].EtOH was prepared by the reaction of trans...
Trans-ReOCl3(PPh3)(2) reacts with 2,3- and 2,6-dihydroxybenzoic acid (H(2)dhb) in an equimolar ratio...
The complex cis-[ReOBr2(msa)(PPh3)](1) was prepared from trans-[ReOBr3(PPh3)2] and 2-(1-iminoethyl)p...
Rhenium(V) complexes containing the [ReX(PPh3)2] 4+ (X = Br, I) moiety were studied. The reaction of...
Crystals of the title compound, fac,cis-[ReBr(C21H21P)2(CO)3], were obtained by recrystallization of...
The crystal and molecular structures of the two bis(amine) complexes of rhenium(I), [ReBr(CO) 3(NHR ...
Rhenium(V) complexes containing the [ReX(PPh3)2]4+ (X = Br, I) moiety were studied. The reaction of ...
The complex cis-[ReO2(Hdab)(py)(2)] (1) (H(2)dab = 1,2-diaminobenzene) has been prepared by reacting...
The complex cis-[ReO2(Hdab)(py)(2)] (1) (H(2)dab = 1,2-diaminobenzene) has been prepared by reacting...
disorder in main residue; R factor = 0.032; wR factor = 0.086; data-to-parameter ratio = 19.9. In th...
In the title salt, (C8H20N)[ReBr(C7H5O2)(CO)3], the ReI atom is octahedrally surrounded by three fac...
[ReBr(CO)5] reacted with phosphinite or phosphonite ligands in benzene or toluene to yield fac-(1) o...
The structure of the title compound, [Re2Cl6(C3H7NO2)2]·1.5H2O, comprises a dinuclear complex cation...
Ruthenium(VI) complexes with a sterically bulky bidentate Schiff base ligand, 2-[(2,6-diisopropylphe...
The reaction of the double Schiff bases, RL, formed from 2,6-diformyl-4-methyl-phenol and p-RC6H4NH2...
The oxo-bridged dinuclear complex [(μ-O){ReO(sal2hpn)} 2].EtOH was prepared by the reaction of trans...
Trans-ReOCl3(PPh3)(2) reacts with 2,3- and 2,6-dihydroxybenzoic acid (H(2)dhb) in an equimolar ratio...