Abstract approved Redacted for Privacy (Major professor) An examination was made of some reactions involving a trans-fer of carbon from boron to carbon. In the case of the reaction of a C n alkylorganoborane with dichlorocarbene the intermediate was a Cn +1 chloroalkylorganoborane. Oxidation of this intermediate yielded an homologous acid (33 %) and the usual alcohol (66 %). The results of several other transfer studies are presented, and the role of ethereal solvents discussed
Aqueous hydrogen peroxide in the presence of dilute alkali effects the oxidation of organoboranes. T...
The rearrangement of borates derived from the addition of a trialkylborane to a lithiated enol ether...
The kinetics of the autoxidation of a series of n-, s-, and t-butylboron compounds in iso-octane at ...
The introduction of boron into organic synthesis has been shown to have great synthetic utility due ...
Organoboron reagents, especially boronic acids and boronates, have been widely explored as suitable ...
Organoboranes are molecules that contain a carbon-boron bond. They play a pivotal role in organic sy...
Treatment of trialkylcyanoborates with an excess of trifluoroacetic anhydride induces three migratio...
The reactions of ethyl borate with butanols (n & tert.), ethylene glycol, catechol, salicylic acid, ...
A study of the reaction of alpha,beta-unsaturated carbonyl compounds with triethylborane under free ...
grantor: University of TorontoThe hydroboration of a variety of alkynes with either dibrom...
Organoborane compounds are highly used in a huge number of fields, from medicine, in the boron neutr...
The reaction between polyhalomethanes and the borane-dimethyl sulphide complex (BMS) was investigate...
Until recently, organoboronic acids have been of limited use in organic synthesis due to their low r...
Diisopropylaminoborane (BH2-N(iPr)2) is prepared by reacting lithium diisopropylaminoborohydride (iP...
Abstract • Organoboranes which are important for preparative purposes indlude triethylborane, alkyld...
Aqueous hydrogen peroxide in the presence of dilute alkali effects the oxidation of organoboranes. T...
The rearrangement of borates derived from the addition of a trialkylborane to a lithiated enol ether...
The kinetics of the autoxidation of a series of n-, s-, and t-butylboron compounds in iso-octane at ...
The introduction of boron into organic synthesis has been shown to have great synthetic utility due ...
Organoboron reagents, especially boronic acids and boronates, have been widely explored as suitable ...
Organoboranes are molecules that contain a carbon-boron bond. They play a pivotal role in organic sy...
Treatment of trialkylcyanoborates with an excess of trifluoroacetic anhydride induces three migratio...
The reactions of ethyl borate with butanols (n & tert.), ethylene glycol, catechol, salicylic acid, ...
A study of the reaction of alpha,beta-unsaturated carbonyl compounds with triethylborane under free ...
grantor: University of TorontoThe hydroboration of a variety of alkynes with either dibrom...
Organoborane compounds are highly used in a huge number of fields, from medicine, in the boron neutr...
The reaction between polyhalomethanes and the borane-dimethyl sulphide complex (BMS) was investigate...
Until recently, organoboronic acids have been of limited use in organic synthesis due to their low r...
Diisopropylaminoborane (BH2-N(iPr)2) is prepared by reacting lithium diisopropylaminoborohydride (iP...
Abstract • Organoboranes which are important for preparative purposes indlude triethylborane, alkyld...
Aqueous hydrogen peroxide in the presence of dilute alkali effects the oxidation of organoboranes. T...
The rearrangement of borates derived from the addition of a trialkylborane to a lithiated enol ether...
The kinetics of the autoxidation of a series of n-, s-, and t-butylboron compounds in iso-octane at ...