FULFILMENT OF THE REQUIREMENTS FOR THE DEGREE OF

Poly(para-phenylene) (PPP) has generated sustained scientific interest due to its potential as a blue-emitting material for use in Organic Light Emitting Devices (OLEDs). However, due to its highly unfavorable solubility, most traditional synthetic routes to PPP are relatively limited in their scope. In Chapter 2 we discuss the synthesis of poly(para-arylene)s via the post polymerization functionalization of a completely soluble and easily accessible precursor polymer, utilizing the metal-catalyzed [2+2+2] reaction. We expect that this versatile strategy could lead to new and interesting PPP derivatives. In Chapter 3, we employed this [2+2+2] strategy once more in the synthesis of an defective, but otherwise inaccessible alkoxy substituted poly(phenylene triptycene). We discuss the limitations of this synthetic route for the installation of the three-dimensional triptycene scaffold along the polyphenylene backbone. Recent interest in belt-shaped p-polyarylene macrocycles, otherwise known a