Add to ORKGR factor = 0.029; wR factor = 0.080; data-to-parameter ratio = 17.1. In the title compound, C14H14N2S3, the thione S atom and methyl group are syn, as are the two thioether S atoms. The molecule is twisted, the dihedral angles between the central (C2N2S2) residue and the pendent 2-thienyl and phenyl rings being 21.57 (6) and 77.54 (3), respectively. In the crystal, molecules assemble into a three-dimensional architecture via C—H interactions, involving both the five- and six-membered rings as acceptors, as well as S S interactions [3.3406 (5) Å] between centrosymmetrically related 2-thienyl rings. Related literature For the biological activity of related Schiff base compounds, see: Hazari et al. (2002). For a related structure, see...