R factor = 0.075; wR factor = 0.184; data-to-parameter ratio = 18.4. The title cluster, [Cu4(C11H12N2O6)4], was obtained from the Cu0–FeCl24H2O–H4L–Et3N–DMF reaction system (in air), where H4L is 2-hydroxymethyl-2{[(2-hydroxy-3-nitrophen-yl)methylidene]amino}propane-1,3-diol and DMF is dimethyl-formamide. The asymmetric unit consists of one Cu2+ ion and one dianionic ligand; a 4 symmetry element generates the cluster, which contains a {Cu4O4} cubane-like core. The metal ion has an elongated square-based pyramidal CuNO4 coordination geometry with the N atom in a basal site. An intramolecular O—H O hydrogen bond is observed. The solvent molecules were found to be highly disordered and their contribution to the scattering was removed with t...
R factor = 0.036; wR factor = 0.081; data-to-parameter ratio = 13.1. In the title complex, [Cu(C14H1...
DFT calculations on Cu4(μ3-X)4L 4 (X = H, CH3, CCH, F, Cl, Br, I; L = NH3, PH3) indicate that, regar...
Many polynuclear Cu(l) compounds have been synthesized, but the problem whether there is direct or n...
disorder in main residue; R factor = 0.040; wR factor = 0.129; data-to-parameter ratio = 10.0. The t...
R factor = 0.058; wR factor = 0.204; data-to-parameter ratio = 18.6. The title compound, [Cu(C4H10NO...
disorder in solvent or counterion; R factor = 0.054; wR factor = 0.092; data-to-parameter ratio = 15...
The title molecular structure, namely, diaquatris(μ3-1,3-bis{[1-(2-oxidophenyl)ethylidene]amino}prop...
Artículo científico CrystEngCommCompound 1 [Cu24(m BDC)24(DMF)20(H2O)4]• 24DMF•40H2O (m-BDC is 1,3-b...
The title compound, [Cu4(C11H13NO4)4]·CH3CH2OH·2.5H2O, is an electronically neutral tetranuclear cop...
R factor = 0.028; wR factor = 0.077; data-to-parameter ratio = 17.0. In the title compound, [Cu(C8H8...
cited By 32International audienceA new polynuclear copper(II) complex [Cu7(OH)6Cl2-(pn) 6(H2O)2](C(C...
International audienceThe title molecular structure, namely, diaquatris(μ 3 -1,3-bis{[1-(2-oxidophen...
R factor = 0.033; wR factor = 0.091; data-to-parameter ratio = 12.9. The binuclear title compound, [...
The structures of Cun Om + / 0 and Cun Om Hl + / 0 clusters are obtained by DFT calculations. Cluste...
The combination of Cu(NO(3))(2), potassium hydrogen saccharate (KC(6)H(9)O(8)) and 1,10-phenanthroli...
R factor = 0.036; wR factor = 0.081; data-to-parameter ratio = 13.1. In the title complex, [Cu(C14H1...
DFT calculations on Cu4(μ3-X)4L 4 (X = H, CH3, CCH, F, Cl, Br, I; L = NH3, PH3) indicate that, regar...
Many polynuclear Cu(l) compounds have been synthesized, but the problem whether there is direct or n...
disorder in main residue; R factor = 0.040; wR factor = 0.129; data-to-parameter ratio = 10.0. The t...
R factor = 0.058; wR factor = 0.204; data-to-parameter ratio = 18.6. The title compound, [Cu(C4H10NO...
disorder in solvent or counterion; R factor = 0.054; wR factor = 0.092; data-to-parameter ratio = 15...
The title molecular structure, namely, diaquatris(μ3-1,3-bis{[1-(2-oxidophenyl)ethylidene]amino}prop...
Artículo científico CrystEngCommCompound 1 [Cu24(m BDC)24(DMF)20(H2O)4]• 24DMF•40H2O (m-BDC is 1,3-b...
The title compound, [Cu4(C11H13NO4)4]·CH3CH2OH·2.5H2O, is an electronically neutral tetranuclear cop...
R factor = 0.028; wR factor = 0.077; data-to-parameter ratio = 17.0. In the title compound, [Cu(C8H8...
cited By 32International audienceA new polynuclear copper(II) complex [Cu7(OH)6Cl2-(pn) 6(H2O)2](C(C...
International audienceThe title molecular structure, namely, diaquatris(μ 3 -1,3-bis{[1-(2-oxidophen...
R factor = 0.033; wR factor = 0.091; data-to-parameter ratio = 12.9. The binuclear title compound, [...
The structures of Cun Om + / 0 and Cun Om Hl + / 0 clusters are obtained by DFT calculations. Cluste...
The combination of Cu(NO(3))(2), potassium hydrogen saccharate (KC(6)H(9)O(8)) and 1,10-phenanthroli...
R factor = 0.036; wR factor = 0.081; data-to-parameter ratio = 13.1. In the title complex, [Cu(C14H1...
DFT calculations on Cu4(μ3-X)4L 4 (X = H, CH3, CCH, F, Cl, Br, I; L = NH3, PH3) indicate that, regar...
Many polynuclear Cu(l) compounds have been synthesized, but the problem whether there is direct or n...