Add to ORKGABSTRACT: The fate of the aryl gold(I) carbenes generated by retro-Buchner reaction of ortho-substituted 7-aryl-1,3,5-cycloheptatrienes is dependent on the constitution of the ortho substituent. Indenes and fluorenes are obtained by intramolecular reaction of highly electrophilic gold(I) carbenes with alkenes and arenes. According to density functional theory calculations, the gold-catalyzed retro-Buchner process occurs stepwise, although the two carbon−carbon cleavages occur on a rather flat potential energy surface. 1
The intermolecular gold(I)-catalyzed reaction between arylalkynes and alkenes leads to cyclobutenes...
The mechanism and chemoselectivity of gold(i)-catalyzed cycloadditions of β,β-disubstituted ortho-(a...
A gold-catalyzed carbocyclization of alkynes with a pendant diazo group that is completed by reactio...
The fate of the aryl gold(I) carbenes generated by retro-Buchner reaction of ortho-substituted 7-ary...
The fate of the aryl gold(I) carbenes generated by retro-Buchner reaction of ortho-substituted 7-ar...
A novel synthesis of indanes and dihydronaphtalenes based on the intramolecular insertion into C(sp3...
The intermolecular gold(I)-catalyzed reaction between aryl alkynes and alkenes leads to cyclobutenes...
The formal (3+2) cycloaddition between terminal allenes and aryl or styryl gold(I) carbenes generate...
The intermolecular gold(I)-catalyzed reaction between arylalkynes and alkenes leads to cyclobutenes ...
URL: https://pubs-acs-org.sabidi.urv.cat/doi/abs/10.1021/jacs.7b03005 DOI: 10.1021/jacs.7b03005 Fili...
Els derivats de 7-substituts de 1,3,5-cicloheptatrienes reaccionen amb catalitzadors d'or (I) catiòn...
A highly stereoselective gold(I)-catalyzed cis-vinylcyclopropanation of alkenes has been developed. ...
A highly stereoselective gold(I)-catalyzed cis- vinylcyclopropanation of alkenes has been developed....
Gold-catalyzed intramolecular oxidation of terminal alkynes with an arenesulfinyl group as the tethe...
A series of ligated gold(I) carbenes (where the ligand is Ph<sub>3</sub>P, Me<sub>2</sub>S, or an N...
The intermolecular gold(I)-catalyzed reaction between arylalkynes and alkenes leads to cyclobutenes...
The mechanism and chemoselectivity of gold(i)-catalyzed cycloadditions of β,β-disubstituted ortho-(a...
A gold-catalyzed carbocyclization of alkynes with a pendant diazo group that is completed by reactio...
The fate of the aryl gold(I) carbenes generated by retro-Buchner reaction of ortho-substituted 7-ary...
The fate of the aryl gold(I) carbenes generated by retro-Buchner reaction of ortho-substituted 7-ar...
A novel synthesis of indanes and dihydronaphtalenes based on the intramolecular insertion into C(sp3...
The intermolecular gold(I)-catalyzed reaction between aryl alkynes and alkenes leads to cyclobutenes...
The formal (3+2) cycloaddition between terminal allenes and aryl or styryl gold(I) carbenes generate...
The intermolecular gold(I)-catalyzed reaction between arylalkynes and alkenes leads to cyclobutenes ...
URL: https://pubs-acs-org.sabidi.urv.cat/doi/abs/10.1021/jacs.7b03005 DOI: 10.1021/jacs.7b03005 Fili...
Els derivats de 7-substituts de 1,3,5-cicloheptatrienes reaccionen amb catalitzadors d'or (I) catiòn...
A highly stereoselective gold(I)-catalyzed cis-vinylcyclopropanation of alkenes has been developed. ...
A highly stereoselective gold(I)-catalyzed cis- vinylcyclopropanation of alkenes has been developed....
Gold-catalyzed intramolecular oxidation of terminal alkynes with an arenesulfinyl group as the tethe...
A series of ligated gold(I) carbenes (where the ligand is Ph<sub>3</sub>P, Me<sub>2</sub>S, or an N...
The intermolecular gold(I)-catalyzed reaction between arylalkynes and alkenes leads to cyclobutenes...
The mechanism and chemoselectivity of gold(i)-catalyzed cycloadditions of β,β-disubstituted ortho-(a...
A gold-catalyzed carbocyclization of alkynes with a pendant diazo group that is completed by reactio...