Add to ORKGR factor = 0.053; wR factor = 0.111; data-to-parameter ratio = 15.4. The title compound, [CuCl(C3H8N2S)(C18H15P)2]0.5CH3CN, was prepared by the reaction of copper(I) chloride with 1,3-dimethylthiourea (dmtu) and triphenylphosphine (PPh3) in acetonitrile. The CuI atom has a distorted tetrahedral environment formed by two P atoms from triphenylphosphine, one S atom from the dmtu ligand and one Cl atom. In addition, the molecules exhibit intra- and intermolecular N—H Cl interactions. Related literatur
R factor = 0.036; wR factor = 0.084; data-to-parameter ratio = 20.7. In the mononuclear title comple...
R factor = 0.026; wR factor = 0.076; data-to-parameter ratio = 17.7. The CuII atom in the title comp...
R factor = 0.038; wR factor = 0.110; data-to-parameter ratio = 18.1. In the title compound, [CuI(C12...
R factor = 0.086; wR factor = 0.217; data-to-parameter ratio = 15.4. In the title complex, [CuCl(C8H...
The mononuclear mixed-ligand title complex, [CuCl(C7H7N3O2S)(C18H15P)2], displays a distorted tetrah...
The title trinuclear compound, [Cu3(C5H8NS2)Cl2(C6H15P)3], has the dithiocarbamate ligand symmetrica...
The coordination geometry of the Cu atom in the title compound, [CuI(C7H8N2S)(C18H15P)2], is distort...
In the title complex, [CuCl(C3H4N2)(C18H15P)2], the coordination geometry around CuI is distorted te...
R factor = 0.055; wR factor = 0.139; data-to-parameter ratio = 14.8. The title compound, [Cu(NCS)2(C...
R factor = 0.028; wR factor = 0.075; data-to-parameter ratio = 20.9. In the mononuclear title comple...
The molecular structure of the title compound, [CuCl2(C11H20N2S)2], shows the CuII atom with a disto...
disorder in main residue; R factor = 0.036; wR factor = 0.086; data-to-parameter ratio = 25.2. In th...
R factor = 0.043; wR factor = 0.104; data-to-parameter ratio = 23.3. The molecular structure of the ...
The dinuclear molecule of the title compound, [Cu2(C2O4)(C18H15P)4]·2CH2Cl2, lies across an inv...
The title compound, [Cu(C5H5NO2S2)(C18H15P)2]·CHCl3, features a tetrahedrally coordinated CuI atom w...
R factor = 0.036; wR factor = 0.084; data-to-parameter ratio = 20.7. In the mononuclear title comple...
R factor = 0.026; wR factor = 0.076; data-to-parameter ratio = 17.7. The CuII atom in the title comp...
R factor = 0.038; wR factor = 0.110; data-to-parameter ratio = 18.1. In the title compound, [CuI(C12...
R factor = 0.086; wR factor = 0.217; data-to-parameter ratio = 15.4. In the title complex, [CuCl(C8H...
The mononuclear mixed-ligand title complex, [CuCl(C7H7N3O2S)(C18H15P)2], displays a distorted tetrah...
The title trinuclear compound, [Cu3(C5H8NS2)Cl2(C6H15P)3], has the dithiocarbamate ligand symmetrica...
The coordination geometry of the Cu atom in the title compound, [CuI(C7H8N2S)(C18H15P)2], is distort...
In the title complex, [CuCl(C3H4N2)(C18H15P)2], the coordination geometry around CuI is distorted te...
R factor = 0.055; wR factor = 0.139; data-to-parameter ratio = 14.8. The title compound, [Cu(NCS)2(C...
R factor = 0.028; wR factor = 0.075; data-to-parameter ratio = 20.9. In the mononuclear title comple...
The molecular structure of the title compound, [CuCl2(C11H20N2S)2], shows the CuII atom with a disto...
disorder in main residue; R factor = 0.036; wR factor = 0.086; data-to-parameter ratio = 25.2. In th...
R factor = 0.043; wR factor = 0.104; data-to-parameter ratio = 23.3. The molecular structure of the ...
The dinuclear molecule of the title compound, [Cu2(C2O4)(C18H15P)4]·2CH2Cl2, lies across an inv...
The title compound, [Cu(C5H5NO2S2)(C18H15P)2]·CHCl3, features a tetrahedrally coordinated CuI atom w...
R factor = 0.036; wR factor = 0.084; data-to-parameter ratio = 20.7. In the mononuclear title comple...
R factor = 0.026; wR factor = 0.076; data-to-parameter ratio = 17.7. The CuII atom in the title comp...
R factor = 0.038; wR factor = 0.110; data-to-parameter ratio = 18.1. In the title compound, [CuI(C12...