Crystal structure of 4-methylbenzyl N0- [(thiophen-2-yl)methylidene]- hydrazinecarbodithioate

methylphenyl)methyl]sulfanyl}methanethioyl)amino][1-(thio-phen-2-yl)ethylidene]amine}, the central CN2S2 residue is almost planar (r.m.s. deviation = 0.0061 Å) and forms dihedral angles of 7.39 (10) and 64.91 (5) with the thienyl and p-tolyl rings, respectively; the dihedral angle between these rings is 57.52 (6). The non-thione S atoms are syn, and with respect to the thione S atom, the benzyl group is anti. In the crystal, centrosymmetrically related molecules self-associate via eight-membered { HNCS}2 synthons. The dimeric aggregates stack along the a axis and are are consolidated into a three-dimensional architecture via methyl-C—H (benzene) and benzene-C—H (thienyl) interactions