Add to ORKGABSTRACT: We report the synthesis and comprehensive study of the electronic structure of a unique series of dinuclear group 5 cyclo-tetraphosphide inverted sandwich complexes. White phosphorus (P4) reacts with niobium(III) and tantalum(III) β-diketiminate (BDI) tert-butylimido complexes to produce the bridging cyclo-P4 phosphide species {[(BDI)(N tBu)M]2(μ‑η 3:η3P4)} (1, M = Nb; 2, M = Ta) in fair yields. 1 is alternatively synthesized upon hydrogenolysis of (BDI)Nb(NtBu)Me2 in the presence of P4. The trinuclear side product {[(BDI)NbNtBu]3(μ‑P12)} (3) is also identified. Protonation of 1 with [HOEt2][B(C6F5)4] does not occur at the phosphide ring but rather involves the BDI ligand to yield {[(BDI#)Nb(NtBu)]2(μ‑η 3:η3P4)}[B(C6F5)4]2 (4). Th...
The reaction of the phosphinidene complex [Cp*P{W(CO)(5)}(2)] (1a) (Cp*=C5Me5) with the anionic cycl...
The addition of [NBu4]Br or [NBu4][BH4] to solutions of [Pt4(μ-PPh2)4(C6F5)4(CO)2] (3) yields the co...
Herein we report the synthesis of different phosphido-complexes and -intermediates with WLE-triple b...
We report the synthesis and comprehensive study of the electronic structure of a unique series of di...
We report the synthesis and comprehensive study of the electronic structure of a unique series of di...
The transformation pathway of tetrahedral P4 to the corresponding Pn ligands has been studied by the...
The [3+1] fragmentation reaction of rare-earth metallacyclopentadienes 1a-c with 0.5equivalents of P...
Chapter 1. This chapter comprises a detailed overview of the design and reactivity of pi-loaded grou...
Studies of the reaction pathway of tetrahedral P4 with cobalt- and molybdenum coordination compounds...
This thesis primarily reports on the synthesis and reactivity of phosphorus-containing tetrahedranes...
The terminal phosphorus monoxide complex [(OP)Mo(N[superscript t Bu]Ar) subscript 3], 1 (Ar = 3,5-M...
Converting elemental white phosphorus directly into organophosphorus or polyphosphorus is meaningful...
Although the chemistry of transition metal polyphosphide anions has attracted significant attention,...
Five dispirocyclic λ3,λ5-tetraphosphetes [{R2Si(NR1)(NR2)P2}2] (R1 = R2 and R1 ≠ R2) are easily prep...
Ziel der vorliegenden Arbeit war es, höhervalente Imido- und Amidoverbindungen des Niobs und Tantals...
The reaction of the phosphinidene complex [Cp*P{W(CO)(5)}(2)] (1a) (Cp*=C5Me5) with the anionic cycl...
The addition of [NBu4]Br or [NBu4][BH4] to solutions of [Pt4(μ-PPh2)4(C6F5)4(CO)2] (3) yields the co...
Herein we report the synthesis of different phosphido-complexes and -intermediates with WLE-triple b...
We report the synthesis and comprehensive study of the electronic structure of a unique series of di...
We report the synthesis and comprehensive study of the electronic structure of a unique series of di...
The transformation pathway of tetrahedral P4 to the corresponding Pn ligands has been studied by the...
The [3+1] fragmentation reaction of rare-earth metallacyclopentadienes 1a-c with 0.5equivalents of P...
Chapter 1. This chapter comprises a detailed overview of the design and reactivity of pi-loaded grou...
Studies of the reaction pathway of tetrahedral P4 with cobalt- and molybdenum coordination compounds...
This thesis primarily reports on the synthesis and reactivity of phosphorus-containing tetrahedranes...
The terminal phosphorus monoxide complex [(OP)Mo(N[superscript t Bu]Ar) subscript 3], 1 (Ar = 3,5-M...
Converting elemental white phosphorus directly into organophosphorus or polyphosphorus is meaningful...
Although the chemistry of transition metal polyphosphide anions has attracted significant attention,...
Five dispirocyclic λ3,λ5-tetraphosphetes [{R2Si(NR1)(NR2)P2}2] (R1 = R2 and R1 ≠ R2) are easily prep...
Ziel der vorliegenden Arbeit war es, höhervalente Imido- und Amidoverbindungen des Niobs und Tantals...
The reaction of the phosphinidene complex [Cp*P{W(CO)(5)}(2)] (1a) (Cp*=C5Me5) with the anionic cycl...
The addition of [NBu4]Br or [NBu4][BH4] to solutions of [Pt4(μ-PPh2)4(C6F5)4(CO)2] (3) yields the co...
Herein we report the synthesis of different phosphido-complexes and -intermediates with WLE-triple b...