Colloid Polym Sci (2006) 284: 1275–1286 DOI 10.1007/s00396-006-1508-5 ORIGINAL CONTRIBUTION

Electroosmotic flow velocity measurements in a square microchannel Abstract Experiments were per-formed using a microparticle image velocimetry (MPIV) for 2D velocity distributions of electroosmotically driven flows in a 40-mm-long micro-channel with a square cross section of 200×200 μm. Electroosmotic flow (EOF) bulk fluid velocity measure-ments were made in a range of streamwise electric field strengths from 5 to 25 kV/m. A series of seed particle calibration tests can be made in a 200×120×24,000-μm untreated polydimethyl siloxane (PDMS chan-nel incorporating MPIV to determine the electrophoretic mobilities in aqueous buffer solutions of 1 × TAE, 1 × TBE, 10 mM NaCl, and 10 mM borate. A linear/nonlinear (due to Joule heating) flow rate increase with applied field was obtained and com-pared with those of previous studies. A parametric study, with extensive measurements, was performed with different electric field strength and buffer solution concentration under a constant zeta potential at wall for each buffer. The characteristics of EOF in square microchannels were thus investigated. Finally, a composite correlation of the relevant parameters was developed in the form of u 5:46 ς 0:739DN2:132ME0:9996x within ±1 % accuracy for 99 % of the experimental data