Add to ORKGR factor = 0.031; wR factor = 0.073; data-to-parameter ratio = 18.6. The title benzyl Grignard reagent, [Mg2Br2(C7H7)2-(C4H10O)2], was obtained by reaction of benzyl bromide with magnesium in diethyl ether, followed by crystallization from toluene. The asymmetric unit comprises one half-molecule, the structural dimeric unit being generated by inversion symmetry with an Mg Mg distance of 3.469 (2) Å. The Mg(II) atom exhibits a distorted tetrahedral coordination geometry. The crystal packing is defined by van der Waals interactions only. Related literature For the structures of some other diethyl ether adducts o
In the title Grignard reagent, [MgBr(C12H9)(C5H10O)2], the Mg centre adopts a distorted tetrahedral ...
R factor = 0.058; wR factor = 0.146; data-to-parameter ratio = 16.9. The title compound, C14H10N4, w...
The results of an EXAFS study of the Grignard compounds methyl, ethyl and phenyl magnesium bromide i...
The title benzyl Grignard reagent, [Mg2Br2(C7H7)2(C4H10O)2], was obtained by reaction of benzyl brom...
The structure of the dimeric ethylmagnesium bromide/diisopropyl ether complex [C2H5MgBr - O(i-C3H7)2...
The crystal structure of the title compound, [Mg2Br2(C9H11)2(C4H10O)2], features a centrosymmetric t...
The coordination geometry at the Mg atom in the title complex, [MgBrz{(C3Hv)2NH}{(C2Hs)20}], is show...
R factor = 0.075; wR factor = 0.204; data-to-parameter ratio = 14.1. In the title compound, C14H12Br...
disorder in main residue; R factor = 0.022; wR factor = 0.049; data-to-parameter ratio = 21.1. The M...
The Mg centre in the title compound, [MgBr2(C2H7N)3], is pentacoordinated in a trigonal-bipyramidal ...
Much has been said but little settled about the precise nature of the Grignard reagent. The X-ray st...
The preparation and the X-ray single crystal structure determination of [Mg(C7H7OH)6]Cl2 are describ...
R factor = 0.054; wR factor = 0.141; data-to-parameter ratio = 17.8. In the title compound, C17H16Br...
R factor = 0.026; wR factor = 0.064; data-to-parameter ratio = 24.3. In the title compound, C12H9Br2...
R factor = 0.042; wR factor = 0.096; data-to-parameter ratio = 15.5. In the title molecule, C8H7BrO2...
In the title Grignard reagent, [MgBr(C12H9)(C5H10O)2], the Mg centre adopts a distorted tetrahedral ...
R factor = 0.058; wR factor = 0.146; data-to-parameter ratio = 16.9. The title compound, C14H10N4, w...
The results of an EXAFS study of the Grignard compounds methyl, ethyl and phenyl magnesium bromide i...
The title benzyl Grignard reagent, [Mg2Br2(C7H7)2(C4H10O)2], was obtained by reaction of benzyl brom...
The structure of the dimeric ethylmagnesium bromide/diisopropyl ether complex [C2H5MgBr - O(i-C3H7)2...
The crystal structure of the title compound, [Mg2Br2(C9H11)2(C4H10O)2], features a centrosymmetric t...
The coordination geometry at the Mg atom in the title complex, [MgBrz{(C3Hv)2NH}{(C2Hs)20}], is show...
R factor = 0.075; wR factor = 0.204; data-to-parameter ratio = 14.1. In the title compound, C14H12Br...
disorder in main residue; R factor = 0.022; wR factor = 0.049; data-to-parameter ratio = 21.1. The M...
The Mg centre in the title compound, [MgBr2(C2H7N)3], is pentacoordinated in a trigonal-bipyramidal ...
Much has been said but little settled about the precise nature of the Grignard reagent. The X-ray st...
The preparation and the X-ray single crystal structure determination of [Mg(C7H7OH)6]Cl2 are describ...
R factor = 0.054; wR factor = 0.141; data-to-parameter ratio = 17.8. In the title compound, C17H16Br...
R factor = 0.026; wR factor = 0.064; data-to-parameter ratio = 24.3. In the title compound, C12H9Br2...
R factor = 0.042; wR factor = 0.096; data-to-parameter ratio = 15.5. In the title molecule, C8H7BrO2...
In the title Grignard reagent, [MgBr(C12H9)(C5H10O)2], the Mg centre adopts a distorted tetrahedral ...
R factor = 0.058; wR factor = 0.146; data-to-parameter ratio = 16.9. The title compound, C14H10N4, w...
The results of an EXAFS study of the Grignard compounds methyl, ethyl and phenyl magnesium bromide i...
