R factor = 0.055; wR factor = 0.155; data-to-parameter ratio = 14.0. The title compound, [Fe(CF3O3S)(C48H36N4O4)], is a five-coordinate iron(III) porphyrin complex with a trifluoro-methanesulfonate anion as an axial ligand. The FeIII atom is displaced by 0.40 (1) A ̊ towards the trifluoromethanesulfonate anion from the 24-atom mean plane of the porphyrin. The average Fe—Np distance is 2.044 (2) A ̊ and the Fe—O distance is 2.001 (2) Å. Related literature For the structures of related porphyrin (‘picket-fence’, tetra-phenylporphyrin, octaethylporphyrin) derivatives, see
The title compound, [Fe(CF3SO3)2(C4H8O)4], is octahedral with two trifluoromethanesulfonate liga...
In the title compound, [Fe(C5H6ClO2)3], the FeIII cation is situated on a twofold rotation axis and ...
The phenyliron derivative, [Fe(oetpp)C6H5)]SbCl6 (2) generated in dichloromethane by oxidation of th...
The title compound, [Fe(CF3O3S)(C36H44N4)], is an iron(III) porphyrin complex with the trifluorometh...
The title compound, [Fe(C6HF4O)(C48H36N4O4)]·C6H12, represents a five-coordinate iron(III) porp...
disorder in main residue; R factor = 0.056; wR factor = 0.116; data-to-parameter ratio = 14.1. The t...
The title complex, [Fe(C64H64N8O4)(C9H8N2)2](CF3O3S)·2C6H5Cl, has an unusual relative orientation of...
The crystal structure of the title compound, [Fe(C44H20F8N4)- (CH3O)], has been determined. The Fe a...
In the title compound, [Fe(C48H36N4)(C4H6N2)2]ClO4·1.5C4H8O, the iron(III) metal is coordinated in a...
In the title compound, [FeIII(C48H36N4O2)(H2O)2][K(C12H24O6)(H2O)2](SO3CF3)2·2C12H24O6, the FeIII at...
The title compound, [Fe(C64H64N8O4)Cl], is a five-coordinate square-pyramidal porphyrin complex with...
432-437The synthesis and X-ray structure of a six-coordinate (porphinato)iron(III) derivative havin...
The solvated title compound, [Fe(C44H28N4)(C4H6N2)(C7H7NO)]·CH2Cl2, is a porphyrin complex containin...
Few families of compounds have been as intensely studied as iron porphyrin complexes. In spite of th...
The title complex, [Fe(C44H28N4)(C5H8N2)2]·C4H8O, possesses inversion symmetry with the iron(II) ato...
The title compound, [Fe(CF3SO3)2(C4H8O)4], is octahedral with two trifluoromethanesulfonate liga...
In the title compound, [Fe(C5H6ClO2)3], the FeIII cation is situated on a twofold rotation axis and ...
The phenyliron derivative, [Fe(oetpp)C6H5)]SbCl6 (2) generated in dichloromethane by oxidation of th...
The title compound, [Fe(CF3O3S)(C36H44N4)], is an iron(III) porphyrin complex with the trifluorometh...
The title compound, [Fe(C6HF4O)(C48H36N4O4)]·C6H12, represents a five-coordinate iron(III) porp...
disorder in main residue; R factor = 0.056; wR factor = 0.116; data-to-parameter ratio = 14.1. The t...
The title complex, [Fe(C64H64N8O4)(C9H8N2)2](CF3O3S)·2C6H5Cl, has an unusual relative orientation of...
The crystal structure of the title compound, [Fe(C44H20F8N4)- (CH3O)], has been determined. The Fe a...
In the title compound, [Fe(C48H36N4)(C4H6N2)2]ClO4·1.5C4H8O, the iron(III) metal is coordinated in a...
In the title compound, [FeIII(C48H36N4O2)(H2O)2][K(C12H24O6)(H2O)2](SO3CF3)2·2C12H24O6, the FeIII at...
The title compound, [Fe(C64H64N8O4)Cl], is a five-coordinate square-pyramidal porphyrin complex with...
432-437The synthesis and X-ray structure of a six-coordinate (porphinato)iron(III) derivative havin...
The solvated title compound, [Fe(C44H28N4)(C4H6N2)(C7H7NO)]·CH2Cl2, is a porphyrin complex containin...
Few families of compounds have been as intensely studied as iron porphyrin complexes. In spite of th...
The title complex, [Fe(C44H28N4)(C5H8N2)2]·C4H8O, possesses inversion symmetry with the iron(II) ato...
The title compound, [Fe(CF3SO3)2(C4H8O)4], is octahedral with two trifluoromethanesulfonate liga...
In the title compound, [Fe(C5H6ClO2)3], the FeIII cation is situated on a twofold rotation axis and ...
The phenyliron derivative, [Fe(oetpp)C6H5)]SbCl6 (2) generated in dichloromethane by oxidation of th...