The present invention relates to organic silicon-boron polymers which upon pyrolysis produce high-temperature ceramic materials. More particularly, it relates to the polyorganoborosilanes containing -Si-B- bonds which generate high-temperature ceramic materials (e.g., SiC, SiB4, B4C) upon thermal degradation. The process for preparing these organic silicon-boron polymer precursors are also part of the invention
This DOE-sponsored project was focused on the design, synthesis, characterization, and applications ...
Silicon carbide based ceramics have properties such as their high strength and thermal stability tha...
The new borazine derivative [ B{CH(CH3)(SiCl3)} NH](3) (TSEB) was prepared by reacting Cl3Si - CH(C...
The present invention relates to a process for the production of an organoborosilicon preceramic pol...
A process for producing polycrystalline silicon carbide includes heating an amorphous ceramic fiber ...
Novel high strength ceramic fibers derived from boron, silicon, and carbon organic precursor polymer...
Boron-containing organosilicon polymers are widely used under harsh environments as preceramic polym...
Boron-containing organosilicon polymers are widely used under harsh environments as preceramic polym...
National audienceSilicon-based non-oxide ceramics (SiC, Si3N4) have attracted much attention, primar...
Fine physicochemical characterization has allowed proposing of a mechanism for the nitridation pathw...
Poly(borosilazanes) with Si/B molar ratios of 3 and 9 were synthesized, via hydroboration, from viny...
Ceramic matrix composites (CMCs), constituted of a silicon boron oxycarbide (SiBCO) matrix and unidi...
International audienceSilicon-based non-oxide ceramics (SiC, Si3N4) have attractedmuch attention due...
The synthesis, by two different reaction pathways, of boron-modified polysilylcarbodi-imides of gene...
International audienceA series of boron-modified polyorganosilazanes was synthesized from a poly(vin...
This DOE-sponsored project was focused on the design, synthesis, characterization, and applications ...
Silicon carbide based ceramics have properties such as their high strength and thermal stability tha...
The new borazine derivative [ B{CH(CH3)(SiCl3)} NH](3) (TSEB) was prepared by reacting Cl3Si - CH(C...
The present invention relates to a process for the production of an organoborosilicon preceramic pol...
A process for producing polycrystalline silicon carbide includes heating an amorphous ceramic fiber ...
Novel high strength ceramic fibers derived from boron, silicon, and carbon organic precursor polymer...
Boron-containing organosilicon polymers are widely used under harsh environments as preceramic polym...
Boron-containing organosilicon polymers are widely used under harsh environments as preceramic polym...
National audienceSilicon-based non-oxide ceramics (SiC, Si3N4) have attracted much attention, primar...
Fine physicochemical characterization has allowed proposing of a mechanism for the nitridation pathw...
Poly(borosilazanes) with Si/B molar ratios of 3 and 9 were synthesized, via hydroboration, from viny...
Ceramic matrix composites (CMCs), constituted of a silicon boron oxycarbide (SiBCO) matrix and unidi...
International audienceSilicon-based non-oxide ceramics (SiC, Si3N4) have attractedmuch attention due...
The synthesis, by two different reaction pathways, of boron-modified polysilylcarbodi-imides of gene...
International audienceA series of boron-modified polyorganosilazanes was synthesized from a poly(vin...
This DOE-sponsored project was focused on the design, synthesis, characterization, and applications ...
Silicon carbide based ceramics have properties such as their high strength and thermal stability tha...
The new borazine derivative [ B{CH(CH3)(SiCl3)} NH](3) (TSEB) was prepared by reacting Cl3Si - CH(C...